D - Quinic Acid, A Versatile Chiron in Organic Synthesis; D - Quinic Acid, A Versatile Chiron in Organic Synthesis | |
Huang PQ(黄培强) | |
1999-04 | |
关键词 | 奎尼酸 合成 手性合成子 |
英文摘要 | 综述了D-奎尼酸在各种环状和链状生物活性化合物合成中的应用。奎尼酸分子中特有的顺式γ-羟基羧酸的结构单元提供了区别分子中各种羟基,以及进行其它区域选择性和立体选择性控制的方便途经。奎尼酸的结构特征以及其价廉、易得的优点,使之成为一个有用的而且重要的手性合成子。This review describes the use of D - Quinic acid in the synthesis of various natural or un -natural bioactive compounds. Because of the presence of cis - r - hydroxyl - carboxyl subunit in quinic acid, a lactone ring can be formed easily. The thus formed rigid system provides good control elements for many regie - and stereoselective transformations. Besides, D - quinic acid is also readily available. These make this compound a useful and versatile chiron for both cyclic (hexanoids and pentanoids) and acyclic bioactive compounds. |
语种 | 中文 |
出版者 | 中国化学会 |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/2978] ![]() |
专题 | 化学化工-已发表论文 |
推荐引用方式 GB/T 7714 | Huang PQ. D - Quinic Acid, A Versatile Chiron in Organic Synthesis, D - Quinic Acid, A Versatile Chiron in Organic Synthesis[J],1999. |
APA | 黄培强.(1999).D - Quinic Acid, A Versatile Chiron in Organic Synthesis.. |
MLA | 黄培强."D - Quinic Acid, A Versatile Chiron in Organic Synthesis".(1999). |
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