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	AIBN/NaNO_2/FeSO_4·7H_2O/(CH_3CO)_2O存在下甲基丙烯酸甲酯本体聚合的研究; Studies on Living Free Radical Polymerization of MMA in the Presence of AIBN/NaNO_2/FeSO_4·7H_2O/(CH_3CO)_2O
	颜明发 ; 黄剑莹 ; 林明华 ; 林强 ; 陈一虹 ; 邹友思
	2004-05
关键词	活性自由基聚合 亚硝酸钠 稳定自由基 乙酸酐 living free radical polymerization NaNO_2 stable free radical （CH_3CO）_2O
英文摘要	［中文文摘］研究了AIBN/NaNO2/FeSO4·7H2O/(CH3CO)2O存在下甲基丙烯酸甲酯本体聚合行为,发现AIBN/NaNO2/FeSO4·7H2O配比为1/3/3,(CH3CO)2O为1.0mol/L,温度为95℃时,甲基丙烯酸甲酯本体聚合具有活性特征,分子量多分散性指数在1.5以内,控制较好.聚合过程转化率和分子量随时间的增加而增大.［英文文摘］Living free radical Polymerization of MMA was studied in the presence of AIBN/NaNO_2/FeSO_4·7H_2O/(CH_3CO)_2O in this paper. It was found that, when the molar ratio of AIBN/NaNO_2/FeSO_4·7H_2O was 1/3/3/、the amount of (CH_3CO)_2O was 1.0 mol/L and temperature was 95 ℃, polymerization of MMA was living and well controlled. With the increasing of time ,the conversion of monomer and the molecular weight of polymer also increased.
语种	中文
出版者	厦门大学
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/2976]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	颜明发,黄剑莹,林明华,等. AIBN/NaNO_2/FeSO_4·7H_2O/(CH_3CO)_2O存在下甲基丙烯酸甲酯本体聚合的研究, Studies on Living Free Radical Polymerization of MMA in the Presence of AIBN/NaNO_2/FeSO_4·7H_2O/(CH_3CO)_2O[J],2004.
APA	颜明发,黄剑莹,林明华,林强,陈一虹,&邹友思.(2004).AIBN/NaNO_2/FeSO_4·7H_2O/(CH_3CO)_2O存在下甲基丙烯酸甲酯本体聚合的研究..
MLA	颜明发,et al."AIBN/NaNO_2/FeSO_4·7H_2O/(CH_3CO)_2O存在下甲基丙烯酸甲酯本体聚合的研究".(2004).

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