污泥中重金属的去除及回收试验; Removal and recycle of heavy metals in sludge | |
黄翠红 ; 孙道华 ; 李清彪 | |
2006-08 | |
关键词 | 污泥 重金属 提取 柠檬酸 离子交换与再生 Sludge Heavy metals Extraction Citric acid Ion exchange treatment and regeneration |
英文摘要 | [中文文摘]论述了利用离子交换技术循环使用柠檬酸去除污泥中重金属,并置换回收重金属的适宜工艺条件。经柠檬酸处理后,污泥中90%以上的重金属被去除;柠檬酸处理液中的重金属用离子交换法回收,考察了树脂种类、流速、操作方式等因素对离子交换、再生效果的影响;在适宜工艺条件下,重金属的交换率均为100%,而洗脱率均接近90%;柠檬酸及离子交换树脂循环使用,重金属也得到回收,降低了处理成本。[英文文摘] Heavy metals in wastewater t reatment sludge were first ext racted by cit ric acid and subsequently re2 moved f rom the cit ric acid byion exchange. They were recovered f rom the ion exchange bed by dilute HCl and , final2 ly , were replaced in the spent HCl by Al to form valuable water t reatment coagulant and recycleable metals. The effects of resin types , flow rate and flow pattern on the IX t reatment and regeneration were determined. Using 0. 2 M citric acid at p H of 3. 0 , more than 90 % of the heavy metal content was ext racted in 24 hours ; the metal removed sludge could be used as a natural fertilizer. The least costly 732 cationic resin performed the best among the four cat2 ionic IX resins studied ; nearly 100 % of heavy metals in the cit ric acid feed were removed and that regeneration recov2 ered more than 90 % of those removed. The process employing cit ric acid for sludge ext raction , 732 cationic resin for removing the metal in the cit ric acid , 3 bed volumes of 5 % HCl for resin regeneration , and Al slices for replacing the recovered heavy metals in the spent HCl is a low cost method ( YMB $35/ ton dry sludge) for removal and recycle of heavy metals in the sludge. |
语种 | 中文 |
出版者 | 浙江省环境保护局、浙江省环境保护科学设计研究院 |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/2902] ![]() |
专题 | 化学化工-已发表论文 |
推荐引用方式 GB/T 7714 | 黄翠红,孙道华,李清彪. 污泥中重金属的去除及回收试验, Removal and recycle of heavy metals in sludge[J],2006. |
APA | 黄翠红,孙道华,&李清彪.(2006).污泥中重金属的去除及回收试验.. |
MLA | 黄翠红,et al."污泥中重金属的去除及回收试验".(2006). |
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