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The effects of TiO2 coating on the electrochemical performance of Li[Li0.2Mn0.54Ni0.13CO0.13]O-2 cathode material for lithium-ion battery
Zheng, J. M. ; Li, J. ; Zhang, Z. R. ; Guo, X. J. ; Yang, Y. ; Yang Y(杨勇)
2008-04
关键词lithium-rich cathode materials TiO2-coating layer lithium-ion battery surface modifications electrochemical performance
英文摘要TiO2-coated Li[Li0.2Mn0.54Ni0.13CO0.13]O-2 materials have been synthesized and investigated as cathode materials for lithium-ion batteries at both 25 degrees C and elevated temperature (55 degrees C). The structure and morphology of the coated samples were characterized and compared. The XRD results indicate that lattice parameters of the materials did not change distinctly after surface coating. The SEM images demonstrate that the surface of Li[Li0.2Mn0.54Ni0.13Co0.13]O-2 samples were covered with nano-sized TiO2 particles. Differential scanning calorimetry (DSC) analysis results show that thermal stability of the materials was improved. It is also shown that the irreversible capacity loss of the materials was obviously reduced and their capacity retention behaviour was improved after surface modification. (C) 2008 Elsevier B.V. All rights reserved.
语种英语
出版者ELSEVIER SCIENCE BV
内容类型期刊论文
源URL[http://dx.doi.org/doi:10.1016/j.ssi.2008.01.091]  
专题化学化工-已发表论文
推荐引用方式
GB/T 7714
Zheng, J. M.,Li, J.,Zhang, Z. R.,et al. The effects of TiO2 coating on the electrochemical performance of Li[Li0.2Mn0.54Ni0.13CO0.13]O-2 cathode material for lithium-ion battery[J],2008.
APA Zheng, J. M.,Li, J.,Zhang, Z. R.,Guo, X. J.,Yang, Y.,&杨勇.(2008).The effects of TiO2 coating on the electrochemical performance of Li[Li0.2Mn0.54Ni0.13CO0.13]O-2 cathode material for lithium-ion battery..
MLA Zheng, J. M.,et al."The effects of TiO2 coating on the electrochemical performance of Li[Li0.2Mn0.54Ni0.13CO0.13]O-2 cathode material for lithium-ion battery".(2008).
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