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	Synthesis and crystal structure of diisopropyl hydroxy(4-methoxyphenyl)methylphosphonate
	Fang, Hua（State Ocean Adm, Inst Oceanog 3） ; Fang, Mei Juan ; Yi, Rui Zao（State Ocean Adm, Inst Oceanog 3） ; Zhao, Yu Fen ; Zhao YF(赵玉芬)
	2008-04
关键词	synthesis crystal structure alpha-hydroxyphosphonate
英文摘要	The title compound, C14H23O5P, was synthesized by the reaction of 4-methoxybenzaldehyde and diisopropyl phosphite. Its structure was determined with X-ray crystallographic, NMR, MS, and elemental analysis (EA) techniques. The crystal belongs to monoclinic, space group P2(1/n) with the following crystallographic parameters: a = 10.529 (2) angstrom, b = 8.424 (2) angstrom, c = 19.448 (4) angstrom, alpha = 90 degrees, beta = 105.2 (3)degrees, gamma = 90 degrees, mu = 0.180 mm(-1), V = 1664.1 (6) angstrom(3), Z = 4, Dx = 1.207 mg/mm(3), F (000) = 648, T = 293 (2) K, 2.00 degrees <= theta <= 25.50 degrees. The final residual factor is 0.049 for 1933 reflections with I > 2 sigma (I). Crystal packing is stabilized by interatomic hydrogen bond interactions between the doubly bonded phosphoryl O atom and the hydroxyl H atom which link the molecules into chains along the [011] plane of the unit cell.; Foundation of Science and Technology Project of China [2006 DFA43030]; National Natural Science Foundation of China [20572061]
语种	英语
出版者	SPRINGER/PLENUM PUBLISHERS
内容类型	期刊论文
源URL	[http://dx.doi.org/doi:10.1007/s10870-008-9386-y]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Fang, Hua,Fang, Mei Juan,Yi, Rui Zao,et al. Synthesis and crystal structure of diisopropyl hydroxy(4-methoxyphenyl)methylphosphonate[J],2008.
APA	Fang, Hua,Fang, Mei Juan,Yi, Rui Zao,Zhao, Yu Fen,&赵玉芬.(2008).Synthesis and crystal structure of diisopropyl hydroxy(4-methoxyphenyl)methylphosphonate..
MLA	Fang, Hua,et al."Synthesis and crystal structure of diisopropyl hydroxy(4-methoxyphenyl)methylphosphonate".(2008).

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