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	Two 3D Supramolecular Architectures Assembled With 1D or 2D Coordination Polymers by Cooperation of Coordination Bonds, Hydrogen Bonds and pi center dot center dot center dot pi Interactions
	Xu, Xiao-Bin ; Lan, Fei-Fei ; Yang, Shi-Yao ; Li, Ming ; Huang, Rong-Bin ; Zheng, Lan-Sun ; Zheng LS(郑兰荪)
	2010-01
关键词	Coordination polymer Supramolecular interactions Hydrogen bond pi center dot center dot center dot pi interaction
英文摘要	Two 3D supramolecular architectures, [Cu(tmbdc) (NH3)(2)](n), 1, (tmbdc = 2,3,5,6-tetramethylbenzenedicarboxylate), and {[Cu-3(btc)(2)(NH3)(6)(H2O)]center dot 2H(2)O}(n), 2, (btc = 1,3,5-benzenetricarboxylate) have been assembled with 1D or 2D coordination polymers as supramolecular synthons. The geometry matching of the moieties is the key factor for the formation of the two supramolecular architectures by the cooperation of coordination bonds, hydrogen bonds and pi center dot center dot center dot pi interactions. Crystal data for 1: Formula CuC12H18N2O4, monoclinic, space group P2(1)/c, a = 9.0134(5), b = 10.8785(5), c = 6.4702(3) angstrom, beta = 91.679 (1)degrees, V = 634.15(5) angstrom(3), Z = 2, R-1 = 0.0251 and wR(2) = 0.0722. Crystal data for 2: Formula Cu3C18H30N6O15, monoclinic, space group C2/c, a = 13.9213(5), b = 17.1210(6), c = 12.5271(5) angstrom, beta = 114.779(1)degrees, V = 2710.89(17) angstrom(3), Z = 4, R-1 = 0.0245 and wR(2) = 0.0665. The positions and isotropic displacement parameters of all the hydrogen atoms are refined.; National Natural Science Foundation of China [20471049, 20721001]; National Basic Research Program of China (973 Program) [2007CB815301]; NFFTBS [J0630429]; Xiamen University
语种	英语
出版者	SPRINGER/PLENUM PUBLISHERS
内容类型	期刊论文
源URL	[http://dx.doi.org/doi:10.1007/s10870-010-9695-9]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Xu, Xiao-Bin,Lan, Fei-Fei,Yang, Shi-Yao,et al. Two 3D Supramolecular Architectures Assembled With 1D or 2D Coordination Polymers by Cooperation of Coordination Bonds, Hydrogen Bonds and pi center dot center dot center dot pi Interactions[J],2010.
APA	Xu, Xiao-Bin.,Lan, Fei-Fei.,Yang, Shi-Yao.,Li, Ming.,Huang, Rong-Bin.,...&郑兰荪.(2010).Two 3D Supramolecular Architectures Assembled With 1D or 2D Coordination Polymers by Cooperation of Coordination Bonds, Hydrogen Bonds and pi center dot center dot center dot pi Interactions..
MLA	Xu, Xiao-Bin,et al."Two 3D Supramolecular Architectures Assembled With 1D or 2D Coordination Polymers by Cooperation of Coordination Bonds, Hydrogen Bonds and pi center dot center dot center dot pi Interactions".(2010).

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