Structural Assembly from Phosphate to Germanophosphate by Applying Germanate as a Binder

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	Structural Assembly from Phosphate to Germanophosphate by Applying Germanate as a Binder
	Huang, Ya-Xi ; Liu, Biao ; Wen, Lei ; Zhang, Xin ; Sun, Wei ; Lin, Jun ; Huang, Chun-Zuo ; Zhuang, Rong-Chuan ; Mi, Jin-Xiao ; Zhao, Jing-Tai ; Huang YX(黄雅熙) ; Mi JX(宓锦校)
刊名	http://dx.doi.org/10.1021/ic401329d
	2013
关键词	OPEN-FRAMEWORK THERMAL-EXPANSION MAGNETIC-PROPERTIES CRYSTAL-STRUCTURE SILICATE
英文摘要	National Natural Science Foundation of China [21201144, 21233004, 40972035]; Fundamental Research Funds for the Central Universities [2013121020]; Technological Innovation Platform of Fujian Province [2006L2003]; Structural assembly from phosphate to germanophosphate by applying germanate as a binder has been achieved. Two isotypic porous compounds, K-3 [M-4(II)(HPO4)(2)][Ge2O(OH)(PO4)(4)]center dot xH(2)O (M-II = Fe, Cd; x = 2 for Fe and 3 for Cd, denoted as KFeGePO-1 and KCdGePO-1, respectively), contain a known transition-metal phosphate (TMPO) layer, (2)(infinity){[M-2(HPO4)(3)](2-)}, which is built from chains of trans-edge-sharing MO6 octahedra bridged by MO5 trigonal bipyramids that were further linked and decorated by phosphate tetrahedra. The layers are bound by infinite chains of GeO5(OH) octahedra, resulting in a 3D open-framework structure with 1D 12-ring channels that are occupied by K+ ions and water molecules. The curvature of the TMPO layers and shape of the 12-ring windows can be tuned by the transition metals because of their Jahn-Teller effect.
语种	英语
出版者	AMER CHEMICAL SOC
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/87258]
专题	材料学院－已发表论文
推荐引用方式 GB/T 7714	Huang, Ya-Xi,Liu, Biao,Wen, Lei,et al. Structural Assembly from Phosphate to Germanophosphate by Applying Germanate as a Binder[J]. http://dx.doi.org/10.1021/ic401329d,2013.
APA	Huang, Ya-Xi.,Liu, Biao.,Wen, Lei.,Zhang, Xin.,Sun, Wei.,...&宓锦校.(2013).Structural Assembly from Phosphate to Germanophosphate by Applying Germanate as a Binder.http://dx.doi.org/10.1021/ic401329d.
MLA	Huang, Ya-Xi,et al."Structural Assembly from Phosphate to Germanophosphate by Applying Germanate as a Binder".http://dx.doi.org/10.1021/ic401329d (2013).