Adjustable supramolecular polymer microstructures fabricated by the breath figure method

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	Adjustable supramolecular polymer microstructures fabricated by the breath figure method
	Chen, Jianzhuang ; Yan, Xuzhou ; Zhao, Qiaoling ; Li, Lei ; Huang, Feihe ; Li L(李磊)
刊名	http://dx.doi.org/10.1039/c1py00438g
	2012
关键词	HOST-GUEST INTERACTIONS ORGANIZED HONEYCOMB MORPHOLOGY PI-PI STACKING SELF-ORGANIZATION CROWN-ETHER HOMODITOPIC MOLECULES SOFT-LITHOGRAPHY STAR-POLYMER POROUS FILMS RECOGNITION
英文摘要	National Natural Science Foundation of China [20834004, 91027006]; Fundamental Research Funds for the Central Universities [2010QNA3008]; Zhejiang Provincial Natural Science Foundation of China [R4100009]; National Basic Research Program [2009CB930104]; State Key Laboratory of Supramolecular Structure and Materials; Highly ordered supramolecular polymer honeycomb-patterned films were fabricated successfully via the static breath figure method. The supramolecular polymer that was used to prepare these intriguing films was obtained from the self-organization of a heteroditopic monomer based on the benzo-21-crown-7/secondary ammonium salt recognition motif. The morphologies of these microstructures were observed by scanning electron microscopy, optical microscopy and atomic force microscopy techniques. The monomer concentration plays an important role in the fabrication of these supramolecular polymer microstructures. The pore size of honeycomb-patterned films decreases with the increase of the monomer concentration from 4 wt% to 30 wt%. A microsphere (900 nm) pattern and a highly-ordered honeycomb-patterned film (2.0 mu m) were obtained via the static breath figure method using acetonitrile as the solvent at concentrations of 2 wt% and 30 wt%, respectively.
语种	英语
出版者	POLYM CHEM-UK
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/87188]
专题	材料学院－已发表论文
推荐引用方式 GB/T 7714	Chen, Jianzhuang,Yan, Xuzhou,Zhao, Qiaoling,et al. Adjustable supramolecular polymer microstructures fabricated by the breath figure method[J]. http://dx.doi.org/10.1039/c1py00438g,2012.
APA	Chen, Jianzhuang,Yan, Xuzhou,Zhao, Qiaoling,Li, Lei,Huang, Feihe,&李磊.(2012).Adjustable supramolecular polymer microstructures fabricated by the breath figure method.http://dx.doi.org/10.1039/c1py00438g.
MLA	Chen, Jianzhuang,et al."Adjustable supramolecular polymer microstructures fabricated by the breath figure method".http://dx.doi.org/10.1039/c1py00438g (2012).