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	Control of channel shapes in a microporous manganese(II)-borophosphate framework by variation of size and shape of organic template cations
	Huang, Y. X. ; Hochrein, O. ; Zahn, D. ; Prots, Y. ; Borrmann, H. ; Kniep, R. ; Huang YX(黄雅熙)
	2007
关键词	ab initio calculations borophosphate manganese microporous materials template synthesis
英文摘要	The templated microporous compounds [H-2(Templ.)][Mn-II-{B2P3O12(OH)}], [templates: 1,3-diaminopropane, C(3)Hi(10)N(2) (DAP); piperazine, C4H10N2 (PIP); 1,4-diazacyclo[2.2.2]octane, C6H12N2 (DABCO)] were prepared under mild hydrothermal conditions. The crystal structures (H(2)DAP-Mn: Pmc2(l) (no. 26), a = 1259.43(5), b = 949.86(5), c = 1135.92(5) pm, Z = 4; H2PIP-Mn: Ima2 (no. 46), a = 1257.9(1), b = 948.69(8), c = 1158.19(8) pm, Z = 4; H,DABCO-H2PIP-Mn: Ima2 (no. 46) a = 1262.90(7), b= 961.05(5) c = 1151.42(7) pm, Z = 4) are characterized by identical framework connectivities [MnII{B2P3O12(OH)}](2-), but vary in shapes (diameters) of the structural channels depending on the shapes of the templating molecule ions. The situation clearly reflects the directing effect of true templates during endo-templating reactions. The experimental results (preparation, chemical analyses, and X-ray refinements) are supported by detailed ab initio calculations (structure optimizations).
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/59962]
专题	材料学院－已发表论文
推荐引用方式 GB/T 7714	Huang, Y. X.,Hochrein, O.,Zahn, D.,et al. Control of channel shapes in a microporous manganese(II)-borophosphate framework by variation of size and shape of organic template cations[J],2007.
APA	Huang, Y. X..,Hochrein, O..,Zahn, D..,Prots, Y..,Borrmann, H..,...&黄雅熙.(2007).Control of channel shapes in a microporous manganese(II)-borophosphate framework by variation of size and shape of organic template cations..
MLA	Huang, Y. X.,et al."Control of channel shapes in a microporous manganese(II)-borophosphate framework by variation of size and shape of organic template cations".(2007).

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