Single-crystal microtubes of a novel apatite-type compound, (Na25Bi25)(PO4)(3)(F,OH), with well-faceted hexagonal cross sections

CORC > 厦门大学 > 材料学院－已发表论文

	Single-crystal microtubes of a novel apatite-type compound, (Na25Bi25)(PO4)(3)(F,OH), with well-faceted hexagonal cross sections
	Zhou, Y. ; Huang, Y. X. ; Pan, Y. M. ; Mi, J. X. ; Mi JX(宓锦校)
刊名	http://dx.doi.org/10.1039/b900499h
	2009
关键词	GROWTH-MECHANISM HYDROTHERMAL SYNTHESIS TELLURIUM NANOTUBES ORGANIC MICROTUBES NITRIDE NANOTUBES OXIDE NANOTUBES ZNO MICROTUBES HYDROXYAPATITE CALCIUM TEMPLATES
英文摘要	National Natural Science Foundation of China [40472027]; Natural Science and Engineering Research Council of Canada; A novel apatite-type compound, (Na2.5Bi2.5)(PO4)(3)(F,OH), NBPF, in the form of single-crystal microtubes with well-faceted, hexagonal morphologies in both exterior and interior surfaces, has been synthesized under hydrothermal conditions without addition of any template, surfactant or metal catalyst. Single crystal X-ray diffraction analysis confirms that Na+ and Bi3+ ions completely replace the Ca2+ ions in the apatite-like structure and jointly occupy three crystallographic sites with significantly different site preferences [Bi0.61Na0.39 at the 6c site, and Bi0.45Na0.55 and Bi0.23Na0.77 at the 2b sites, space group P6(3) (No. 173)]. Time-dependent experiments show that these NBPF microtubes form via a fluoride-induced, in situ chemical reaction nucleation-dissolution-recrystallization growth mechanism.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/59301]
专题	材料学院－已发表论文
推荐引用方式 GB/T 7714	Zhou, Y.,Huang, Y. X.,Pan, Y. M.,et al. Single-crystal microtubes of a novel apatite-type compound, (Na25Bi25)(PO4)(3)(F,OH), with well-faceted hexagonal cross sections[J]. http://dx.doi.org/10.1039/b900499h,2009.
APA	Zhou, Y.,Huang, Y. X.,Pan, Y. M.,Mi, J. X.,&宓锦校.(2009).Single-crystal microtubes of a novel apatite-type compound, (Na25Bi25)(PO4)(3)(F,OH), with well-faceted hexagonal cross sections.http://dx.doi.org/10.1039/b900499h.
MLA	Zhou, Y.,et al."Single-crystal microtubes of a novel apatite-type compound, (Na25Bi25)(PO4)(3)(F,OH), with well-faceted hexagonal cross sections".http://dx.doi.org/10.1039/b900499h (2009).