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	Studies on the intergrowth structures in indium(In) borophosphates; 铟硼磷酸盐结构中的交叠生长规律研究
	Mao, S. Y. ; Mao SY(毛少瑜) ; Li Man-Rong ; Li MR(李满荣) ; WEI Zan-Bin ; Wei ZB(魏赞斌) ; Mi Jin-Xiao ; Mi JX(宓锦校) ; Zhao Jing-Tai ; Zhao JT(赵景泰)
	2004-01
关键词	intergrowth structure 交叠生长结构 borophosphate 硼磷酸盐 hydrothermal synthesis 水热合成 indium 铟
英文摘要	Several indium borophosphates have been reported recently, including KIn[BP2O8(OH)](I) and NaIn[BP2O8(OH)](H). The latter two compounds were synthesized under mild hydrothermal conditions, and have the same molar ratio (M-I:In:B:P:O:H) in molecular formula but with different structure types. Compound I crystallizes in the triclinic system with space group P (1) over bar (No.2), a=0.52638(4) nm, b=0.84791(5) nm, c=0.81469(9) nm, alpha=91.1741(7)degrees, beta=93.061(7)degrees, gamma=79.823(5)degrees, V=0.3573 nm(3), Z=2; while compound II possesses a monoclinic structure with space group P2(1)/n (No.14) with a=0.5177(1) nm, b=1.6815(3) nm, c=0.7684(2) nm, beta=94.10(3)degrees, V=0.6672(2) nm(3), Z=4. Eight- membered-ring and six-membered-ring are formed by alternating borate, phosphate tetrahedra and In-coordination octahedron sharing corners via common oxygen atoms in compound I and H respectively. The polyhedra in the structure are oriented along certain direction to form alternating layered fragments. These two structure types can be considered as intergrowth structures, which consist of the same layered fragments growing in different orientations. Other structure intergrowth possibilities are also expected in similar systems.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/59299]
专题	材料学院－已发表论文
推荐引用方式 GB/T 7714	Mao, S. Y.,Mao SY,Li Man-Rong,et al. Studies on the intergrowth structures in indium(In) borophosphates, 铟硼磷酸盐结构中的交叠生长规律研究[J],2004.
APA	Mao, S. Y..,毛少瑜.,Li Man-Rong.,李满荣.,WEI Zan-Bin.,...&赵景泰.(2004).Studies on the intergrowth structures in indium(In) borophosphates..
MLA	Mao, S. Y.,et al."Studies on the intergrowth structures in indium(In) borophosphates".(2004).

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