State-dependent gerade/ungerade intensity ratios in the Auger spectrum of N-2 | |
Puttner, R. ; Fukuzawa, H. ; Liu, X. J. ; Semenov, S. K. ; Cherepkov, N. A. ; Tanaka, T. ; Hoshino, M. ; Tanaka, H. ; Ueda, K. ; Liu XJ(刘兴军) | |
2008 | |
关键词 | CORE-HOLE LOCALIZATION PHOTOELECTRON-SPECTRUM MOLECULAR NITROGEN SYMMETRY BREAKING SHAPE RESONANCE SPECTROSCOPY PHOTOIONIZATION N-2(2+) DECAY PHOTOEMISSION |
英文摘要 | We have applied both high-resolution photoelectron and Auger spectroscopy to study the N 1s core ionization of N(2). From the respective spectra we are able to show that the Auger decay involves delocalized description of core-hole states. Specifically, the Auger spectra of the N 1s sigma(g,u) core holes to the quasi-stable final states X (1)Sigma(+)(g) and D (1)Sigma(+)(u) are presented. They exhibit the gerade/ungerade splitting as well as vibrational progressions. The 1s sigma(g)/1s sigma(u) Auger intensity ratios are, in agreement with ab initio calculations, congruent to 2.1 and congruent to 0.8 for the X and the D states respectively. The large value for the X state can qualitatively be related to the gerade or ungerade symmetry of the Auger electron. |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/59128] |
专题 | 材料学院-已发表论文 |
推荐引用方式 GB/T 7714 | Puttner, R.,Fukuzawa, H.,Liu, X. J.,et al. State-dependent gerade/ungerade intensity ratios in the Auger spectrum of N-2[J],2008. |
APA | Puttner, R..,Fukuzawa, H..,Liu, X. J..,Semenov, S. K..,Cherepkov, N. A..,...&刘兴军.(2008).State-dependent gerade/ungerade intensity ratios in the Auger spectrum of N-2.. |
MLA | Puttner, R.,et al."State-dependent gerade/ungerade intensity ratios in the Auger spectrum of N-2".(2008). |
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