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	Cyanide-bridged 1D Mn(III)-Fe(III) bimetallic complexes: synthesis, crystal structure and magnetic properties
	Kou, Hui-Zhong ; Ni, Zhong-Hai ; Liu, Cai-Ming ; Zhang, De-Qing ; Cui, Ai-Li
	2010-10-12 ; 2010-10-12
关键词	SINGLE-CHAIN MAGNETS BUILDING-BLOCK FE PRECURSOR DESIGN TRANSITION SYSTEMS SERIES NI CO Chemistry, Multidisciplinary
中文摘要	Cyanide-bridged Mn(III)-Fe(III) complexes have been synthesized in order to find new molecular materials with interesting magnetic properties. 1D complexes of trans-dicyanoferrite(III), [Mn(5-Cl-salen) Fe(bpClb)(CN)(2)]center dot 0.67MeCN center dot 0.5H(2)O (1), [Mn(5-Cl-salen)Fe(bpb)(CN)(2)]center dot 0.5H(2)O center dot MeOH (2), [Mn(5-Br-salen)Fe(bpb)(CN)(2)]center dot 0.5H(2)O center dot MeOH (3), and [Mn(5-Me-salen)Fe(bpb)(CN)(2)]center dot 0.5H(2)O center dot MeOH (4) have been prepared and characterized by X-ray single-crystal structure analysis and magnetic measurements. All complexes possesses 1D chains of alternate [Mn(5-R-salen)](+) and [Fe(bpRb)(CN)(2)](-) units that are linked by two trans-cyanide ligands of [Fe(bpRb)(CN)(2)](-). Magnetic studies reveal that they exhibit overall intermetallic ferromagnetic coupling, while complex 4 shows a frequency-dependent AC magnetic susceptibility typical of a single-chain magnet.
语种	英语 ; 英语
出版者	ROYAL SOC CHEMISTRY ; CAMBRIDGE ; THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND
内容类型	期刊论文
源URL	[http://hdl.handle.net/123456789/81039]
专题	清华大学
推荐引用方式 GB/T 7714	Kou, Hui-Zhong,Ni, Zhong-Hai,Liu, Cai-Ming,et al. Cyanide-bridged 1D Mn(III)-Fe(III) bimetallic complexes: synthesis, crystal structure and magnetic properties[J],2010, 2010.
APA	Kou, Hui-Zhong,Ni, Zhong-Hai,Liu, Cai-Ming,Zhang, De-Qing,&Cui, Ai-Li.(2010).Cyanide-bridged 1D Mn(III)-Fe(III) bimetallic complexes: synthesis, crystal structure and magnetic properties..
MLA	Kou, Hui-Zhong,et al."Cyanide-bridged 1D Mn(III)-Fe(III) bimetallic complexes: synthesis, crystal structure and magnetic properties".(2010).

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