CuCl-catalyzed reaction of zirconacyclopentenes with oxalyl chloride: a new pathway for the preparation of cyclopentenones | |
Chen, Chao ; Liu, Yundong ; Xi, Chanjuan | |
2010-10-12 ; 2010-10-12 | |
关键词 | Zirconacyclopentenes Oxalyl chloride Cuprous chloride Cyclopentenones KHAND-TYPE REACTION METAL-PROMOTED CYCLIZATION ONE-STEP SYNTHESIS CYCLOPENTADIENONE DERIVATIVES TETRAHYDROFURAN DERIVATIVES STEREOSELECTIVE-SYNTHESIS NAZAROV CYCLIZATION CONVENIENT METHOD INTERNAL ALKYNES CARBON-MONOXIDE Chemistry, Organic |
中文摘要 | Zirconacyclopentenes, which are easily prepared from alkynes and EtMgBr (or ethylene) and Cp2ZrCl2, reacted with oxalyl chloride in the presence of catalytic amount of CuCl to give cyclopentenones in high yields. The reaction was performed conveniently in one pot from alkynes, EtMgBr, oxalyl chloride, and Cp2ZrCl2. (C) 2009 Elsevier Ltd. All rights reserved. |
语种 | 英语 ; 英语 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD ; OXFORD ; THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND |
内容类型 | 期刊论文 |
源URL | [http://hdl.handle.net/123456789/81017] |
专题 | 清华大学 |
推荐引用方式 GB/T 7714 | Chen, Chao,Liu, Yundong,Xi, Chanjuan. CuCl-catalyzed reaction of zirconacyclopentenes with oxalyl chloride: a new pathway for the preparation of cyclopentenones[J],2010, 2010. |
APA | Chen, Chao,Liu, Yundong,&Xi, Chanjuan.(2010).CuCl-catalyzed reaction of zirconacyclopentenes with oxalyl chloride: a new pathway for the preparation of cyclopentenones.. |
MLA | Chen, Chao,et al."CuCl-catalyzed reaction of zirconacyclopentenes with oxalyl chloride: a new pathway for the preparation of cyclopentenones".(2010). |
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