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CuCl-catalyzed reaction of zirconacyclopentenes with oxalyl chloride: a new pathway for the preparation of cyclopentenones
Chen, Chao ; Liu, Yundong ; Xi, Chanjuan
2010-10-12 ; 2010-10-12
关键词Zirconacyclopentenes Oxalyl chloride Cuprous chloride Cyclopentenones KHAND-TYPE REACTION METAL-PROMOTED CYCLIZATION ONE-STEP SYNTHESIS CYCLOPENTADIENONE DERIVATIVES TETRAHYDROFURAN DERIVATIVES STEREOSELECTIVE-SYNTHESIS NAZAROV CYCLIZATION CONVENIENT METHOD INTERNAL ALKYNES CARBON-MONOXIDE Chemistry, Organic
中文摘要Zirconacyclopentenes, which are easily prepared from alkynes and EtMgBr (or ethylene) and Cp2ZrCl2, reacted with oxalyl chloride in the presence of catalytic amount of CuCl to give cyclopentenones in high yields. The reaction was performed conveniently in one pot from alkynes, EtMgBr, oxalyl chloride, and Cp2ZrCl2. (C) 2009 Elsevier Ltd. All rights reserved.
语种英语 ; 英语
出版者PERGAMON-ELSEVIER SCIENCE LTD ; OXFORD ; THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
内容类型期刊论文
源URL[http://hdl.handle.net/123456789/81017]  
专题清华大学
推荐引用方式
GB/T 7714
Chen, Chao,Liu, Yundong,Xi, Chanjuan. CuCl-catalyzed reaction of zirconacyclopentenes with oxalyl chloride: a new pathway for the preparation of cyclopentenones[J],2010, 2010.
APA Chen, Chao,Liu, Yundong,&Xi, Chanjuan.(2010).CuCl-catalyzed reaction of zirconacyclopentenes with oxalyl chloride: a new pathway for the preparation of cyclopentenones..
MLA Chen, Chao,et al."CuCl-catalyzed reaction of zirconacyclopentenes with oxalyl chloride: a new pathway for the preparation of cyclopentenones".(2010).
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