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	Reactivity of [(2-Phosphino)ethenyl]zirconocene Chloride toward CpM(CO)(3)Cl (M = Mo, W): Formation of [(3-Phosphino)propenoyl]dicarbonyl(cyclopentadienyl)metal, {CpM(CO)(2)[(CO)CR=CRPPh2]}
	Yan, Xiaoyu ; Yu, Bingran ; Wang, Lan ; Tang, Ning ; Xi, Chanjuan
	2010-10-12 ; 2010-10-12
关键词	CARBON BOND FORMATION DIFFERENT ALKYNES METAL EXCHANGE ZIRCONACYCLOPENTADIENES DERIVATIVES (ETA(5)-C5H4CH3)(2)MO2FE(CO)(7)(MU(3)-S) (ETA(5)-C5H4CH3)MOFECO(CO)(8)(MU(3)-S) 3-IODOPROPENOATES CYCLOADDITION COMPLEXES Chemistry, Inorganic & Nuclear Chemistry, Organic
中文摘要	Reaction of [(2-phosphino)ethenyl]zirconocene chloride (1) with CpM(CO)(3)Cl (M = Mo, W) in THF yielded the [(3-phosphino)propenoyl]dicarbonyl(cyclopentadienyl)metals {CpM(CO)(2)[(CO)CR=CRPPh2]} (2). When the reaction between [(2-phosphino)ethenyl]zirconocene chloride (1) and CpMo(CO)(3)Cl was carried out in the presence of a catalytic amount of Pd(CH3CN)(2)Cl-2, [(3-phosphino)propenoyl]dicarbonyl(cyclopentadienyl)molybdenum, {CpMo(CO)(2)[(CO)CR=CRPPh2]}, was exclusively observed. When [(2-phosphino)ethenyl]zirconocene chloride (1) and MeCpW(CO)(3)Cl were reacted in the presence of a catalytic amount of CuCl, [(3-phosphino)propenoyl]dicarbonyl(methylcyclopentadienyl)tungsten, {MeCpW(CO)(2)[(CO)CR=CRPPh2]}, was formed. Their structures are determined by X-ray diffraction analysis.
语种	英语 ; 英语
出版者	AMER CHEMICAL SOC ; WASHINGTON ; 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
内容类型	期刊论文
源URL	[http://hdl.handle.net/123456789/80879]
专题	清华大学
推荐引用方式 GB/T 7714	Yan, Xiaoyu,Yu, Bingran,Wang, Lan,et al. Reactivity of [(2-Phosphino)ethenyl]zirconocene Chloride toward CpM(CO)(3)Cl (M = Mo, W): Formation of [(3-Phosphino)propenoyl]dicarbonyl(cyclopentadienyl)metal, {CpM(CO)(2)[(CO)CR=CRPPh2]}[J],2010, 2010.
APA	Yan, Xiaoyu,Yu, Bingran,Wang, Lan,Tang, Ning,&Xi, Chanjuan.(2010).Reactivity of [(2-Phosphino)ethenyl]zirconocene Chloride toward CpM(CO)(3)Cl (M = Mo, W): Formation of [(3-Phosphino)propenoyl]dicarbonyl(cyclopentadienyl)metal, {CpM(CO)(2)[(CO)CR=CRPPh2]}..
MLA	Yan, Xiaoyu,et al."Reactivity of [(2-Phosphino)ethenyl]zirconocene Chloride toward CpM(CO)(3)Cl (M = Mo, W): Formation of [(3-Phosphino)propenoyl]dicarbonyl(cyclopentadienyl)metal, {CpM(CO)(2)[(CO)CR=CRPPh2]}".(2010).

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