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CdTe nanocrystals sensitized chemiluminescence and the analytical application
Wang, Zhouping ; Li, Jun ; Liu, Bin ; Li, Jinghong
2010-10-12 ; 2010-10-12
关键词CdTe NCs Chemiluminescence IgG Phenols compounds ELECTROGENERATED CHEMILUMINESCENCE CDSE NANOCRYSTALS QUANTUM DOTS PHOTOLUMINESCENCE ELECTROCHEMISTRY NANOPARTICLES SIZE Chemistry, Analytical
中文摘要It was found that the mixing of CdTe semiconductor nanocrystals (NCs) with luminol in the presence of KMnO4 can induce a great sensitized effect on chemiluminescence (CL) emission. When the concentration of luminol, KMnO4 and NaOH were fixed at 1 mu M, 1 mu M and 0.05 M, respectively, the most excellent performance can be obtained for the CdTe NCs sensitized CL. By means of CL and photoluminescence spectra, we suppose the enhanced CL signals resulted from the accelerated luminol CL induced by the oxidized species of CdTe NCs. Based on the finding, using thioglycolic acid-capped CdTe NCs as label and immunoglobulin G (IgG) as a model analyte, a CL immunoassay protocol for IgG content detection was developed. The strong inhibition effect of phenol compounds on luminol-KMnO4-CdTe NCs CL system was also observed. All these findings demonstrated the possibility of semiconductor nanocrystals induced chemiluminescence to be utilized for more practical applications. (C) 2008 Elsevier B.V. All rights reserved.
语种英语 ; 英语
出版者ELSEVIER SCIENCE BV ; AMSTERDAM ; PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS
内容类型期刊论文
源URL[http://hdl.handle.net/123456789/80775]  
专题清华大学
推荐引用方式
GB/T 7714
Wang, Zhouping,Li, Jun,Liu, Bin,et al. CdTe nanocrystals sensitized chemiluminescence and the analytical application[J],2010, 2010.
APA Wang, Zhouping,Li, Jun,Liu, Bin,&Li, Jinghong.(2010).CdTe nanocrystals sensitized chemiluminescence and the analytical application..
MLA Wang, Zhouping,et al."CdTe nanocrystals sensitized chemiluminescence and the analytical application".(2010).
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