Na_2O-CaO-SiO_2-MgO-Al_2O_3-ZnO微晶玻璃制备及晶化行为的研究 | |
曹建尉 ; 李要辉 ; 徐博 ; 梁开明 ; CAO Jian-wei ; LI Yao-hui ; XU Bo ; LIANG Kai-ming | |
2010-06-10 ; 2010-06-10 | |
关键词 | 磷渣 微晶玻璃 整体析晶 表面析晶 phosphorus slag glass-ceramics volume crystallization surface crystallization TQ171.1 |
其他题名 | Preparation and Crystallization Behavior of Na_2O-CaO-SiO_2-MgO-Al_2O_3-ZnO Glass-ceramics |
中文摘要 | 本文设计了Na2O-CaO-SiO2-MgO-Al2O3-ZnO体系,采用熔融法制备了以磷渣为主要原料的微晶玻璃,磷渣在微晶玻璃中的使用率达到67~75%,并利用XRD,SEM等确定了玻璃的最佳热处理制度,研究了Na2O对微晶玻璃析晶及特征的影响。结果发现经过750℃核化4h,850℃晶化2h,得到主晶相为硅灰石(CaSiO3)和菱硅钙钠石(Na2Ca2Si3O9)的微晶玻璃。玻璃中表面析晶和整体析晶同时存在,其中Na2O可促进整体析晶和菱硅钙钠石的析出。; The glass-ceramics was prepared from the phosphorus slag as main primary raw materials by melt quenching technique.The optimal heat-treatment schedule of glass-ceramics was determined,and the effects of Na2O on crystallization behavior of glass-ceramics were investigated by X-ray powder diffraction analysis and scanning electron microscopy.It was shown that the glass-ceramics were obtained by nucleation at 750 ℃ for 4 h and crystallization at 850 ℃ for 2 h,which the main crystalline phases are wollastonite and combeite.Na2O promotes volume crystallization and the precipitation of combeite. |
语种 | 中文 ; 中文 |
内容类型 | 期刊论文 |
源URL | [http://hdl.handle.net/123456789/61230] ![]() |
专题 | 清华大学 |
推荐引用方式 GB/T 7714 | 曹建尉,李要辉,徐博,等. Na_2O-CaO-SiO_2-MgO-Al_2O_3-ZnO微晶玻璃制备及晶化行为的研究[J],2010, 2010. |
APA | 曹建尉.,李要辉.,徐博.,梁开明.,CAO Jian-wei.,...&LIANG Kai-ming.(2010).Na_2O-CaO-SiO_2-MgO-Al_2O_3-ZnO微晶玻璃制备及晶化行为的研究.. |
MLA | 曹建尉,et al."Na_2O-CaO-SiO_2-MgO-Al_2O_3-ZnO微晶玻璃制备及晶化行为的研究".(2010). |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论