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	一种耐高温聚噻吩膜的电化学合成
	张卓 ; 唐洪 ; 吴旭峰 ; 梁晓 ; 石高全 ; ZHANG Zhuo ; TANG Hong ; WU Xufeng ; LIANG Xiao ; SHI Gaoquan
	2010-06-10 ; 2010-06-10
关键词	聚3-[4-(4-戊基-环己基)-苯基]-噻吩 三氟化硼乙醚 电化学聚合 导电高分子 热稳定性 Poly3-[4-(4-Pentyl-cyclohexyl)-phenyl]-thiophene,Boron thrifluoride diethyl etherate,Electrochemical polymerization,Mesogenic phase,Conjugated polymer,Thermal stability O633.5
其他题名	ELECTROSYNTHESIS OF A POLYTHIOPHENE DERIVATIVE WITH HIGH THERMAL STABILITY
中文摘要	Poly3-[4-(4-pentyl-cyclohexyl)-phenyl]-thiophene(P3PhChPeT) films have been electrochemically synthesized by direct oxidation of 3PhChPeT in the mixed electrolyte of boron thrifluoride diethyl etherate(BFEE) and ethyl ether(EE)(4∶1,by volume).The oxidation potential of the monomer was measured to be 1.1 V(versus Ag/AgCl).P3PhChPeT in dedoped state is soluble in usual organic solvents such as tetrahydrofuran and chloroform,etc.The structure of the polymer films was studied by infrared,Raman and UV-visible spectroscopies.The molar mass of the polymer was measured to be about 3400 g/mol with polydispersity of 1.23. The fluorescent spectra showed a single broad band at 566 nm with excitation at 450 nm.The thermal analysis result indicated that this polymer had a high thermal stability with a decomposition temperature higher than 500℃.; 国家自然科学基金项目(基金号90401011,20374034,50225311); 国家科委863项目(项目号2003AA311100)资助;
语种	中文 ; 中文
内容类型	期刊论文
源URL	[http://hdl.handle.net/123456789/60740]
专题	清华大学
推荐引用方式 GB/T 7714	张卓,唐洪,吴旭峰,等. 一种耐高温聚噻吩膜的电化学合成[J],2010, 2010.
APA	张卓.,唐洪.,吴旭峰.,梁晓.,石高全.,...&SHI Gaoquan.(2010).一种耐高温聚噻吩膜的电化学合成..
MLA	张卓,et al."一种耐高温聚噻吩膜的电化学合成".(2010).

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