QQ客服 官方微博 反馈留言

	纳米Fe~0作用下4-氯酚的脱氯特性及机理
	程荣 ; 王建龙 ; CHENG Rong ; WANG Jian-long
	2010-06-04 ; 2010-06-04
关键词	纳米铁 4-氯酚 苯酚 脱氯 地下水污染 nanoscale iron 4-chlorophenol (4-CP) phenol dechlorination groundwater pollution X132
其他题名	Reductive Dechlorination of 4-chlorophenol Using Nanosacle Iron
中文摘要	采用化学还原法制备了纳米Fe0,ESEM测定结果表明其颗粒在1～100nm内.实验表明这些纳米Fe0能在20h内将初始浓度为20mg/L的4-氯酚完全降解,Fe0对4-CP的还原脱氯是主要去除途径.苯酚是脱氯反应的主要产物.当4-CP的初始浓度由20mg/L增大到50,100,150mg/L时,其相对去除率明显降低,但绝对降解量有较大提高.温度不仅影响脱氯速率,而且影响4-CP去除的途径.30℃时,脱氯反应为主要反应;10℃时,较易产生氧化产物.Fe原子的迁移过程在4-CP的降解中也是一个重要的限速步骤.此外,纳米Fe0具有很好的稳定性,在受试的379h内,纳米Fe0能够应对不同浓度冲击及反复投加的4-氯酚冲击的能力.; Nanoscale Fe~0 was synthesized through a reductive method and the size of the particles is in the range of 1～100 nm, observed by ESEM image. The experimental results demonstrated that these metal particles can reduce 4-chlorophenol (4-CP) completely in 20 hours, when the initial concentration was 20 mg/L. Dechlorination by Fe~0 is the main reaction pathway, and phenol is the main product. As the concentration of 4-CP increased from 20 mg/L to 50, 100, 150 mg/L, the relative dechlorination ratio decreased obviously. But the reduced amounts of 4-CP increased. Temperature can influence dechlorination rate and change the reductive pathway. Dechlorination is the main reaction at 30℃ while some oxidized compounds may be produced at 10℃. The transfer of iron atom may be an important factor, limiting the dechlorination rate. Moreover, the stability and durability of nanoscale Fe~0 was assessed through batch studies over extended periods of time. The results indicated that nanoscale Fe~0 can resist the shock of 4-CP concentration during 379 hours.; 国家自然科学基金项目(50325824)
语种	中文 ; 中文
内容类型	期刊论文
源URL	[http://hdl.handle.net/123456789/36101]
专题	清华大学
推荐引用方式 GB/T 7714	程荣,王建龙,CHENG Rong,等. 纳米Fe~0作用下4-氯酚的脱氯特性及机理[J],2010, 2010.
APA	程荣,王建龙,CHENG Rong,&WANG Jian-long.(2010).纳米Fe~0作用下4-氯酚的脱氯特性及机理..
MLA	程荣,et al."纳米Fe~0作用下4-氯酚的脱氯特性及机理".(2010).

个性服务

查看访问统计

相关权益政策

暂无数据

收藏/分享

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。