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工业石膏合成羟基磷灰石及其对Pb~(2+),Cu~(2+),Zn~(2+)和Ni~(2+)的吸附作用
刘海弟 ; 李福志 ; 赵璇 ; 陈运法 ; LIU Hai-di ; LI Fu-zhi ; ZHAO Xuan ; CHEN Yun-fa
2010-05-13 ; 2010-05-13
关键词石膏 固体废弃物 羟基磷灰石 制备 水处理 吸附 gypsum solid waste hydroxyapatite preparation water treatment adsorption TQ028.15
其他题名Preparation of Hydroxyapatite with Industrial Gypsum and Its Adsorption upon Pb~(2+),Cu~(2+),Zn~(2+) and Ni~(2+)
中文摘要研究了以工业石膏为原料合成羟基磷灰石(HAp)的方法,并考察了所制备的HAp对水溶液中Pb2+,Cu2+,Zn2+和Ni2+四种金属离子的吸附作用.结果表明,在反应温度90℃、磷酸氢二铵和工业石膏物质的量比为1:2的条件下,反应24h便可以得到较纯的HAp.所制备的HAp在pH7的条件下对水溶液中的Pb2+,Cu2+,Zn2+和Ni2+均具有一定的吸收能力,其饱和吸附量分别为1095,86.76,64.68和67.90mg/g.该吸附过程符合Langmuir吸附模型.; The preparation method of hydroxyapatite(HAp)with industrial gypsum was investigated.The adsorption abilities of as-prepared samples upon Pb2 +,Cu 2+,Zn 2+and Ni 2+ions in aqueous solution were examined.It was indicated that pure HAp could be successfully fabricated when the molar ratio of(NH4)2HPO4 to industrial gypsum was 1:2 with the reaction between them for 24 h under 90℃.The as-synthesized HAp exhibited obvious adsorption ability upon Pb2 +,Cu 2+,Zn 2+and Ni 2+ions under pH 7,and their saturated adsorption amounts were 1 095,86.76,64.68 and 67.90 mg/g respectively.Their adsorption behaviors could be described with the Langmuir model approximately.
语种中文 ; 中文
内容类型期刊论文
源URL[http://hdl.handle.net/123456789/30302]  
专题清华大学
推荐引用方式
GB/T 7714
刘海弟,李福志,赵璇,等. 工业石膏合成羟基磷灰石及其对Pb~(2+),Cu~(2+),Zn~(2+)和Ni~(2+)的吸附作用[J],2010, 2010.
APA 刘海弟.,李福志.,赵璇.,陈运法.,LIU Hai-di.,...&CHEN Yun-fa.(2010).工业石膏合成羟基磷灰石及其对Pb~(2+),Cu~(2+),Zn~(2+)和Ni~(2+)的吸附作用..
MLA 刘海弟,et al."工业石膏合成羟基磷灰石及其对Pb~(2+),Cu~(2+),Zn~(2+)和Ni~(2+)的吸附作用".(2010).
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