An improved dry flue gas desulfurization technique through radical chain reactions | |
Song Qiang ; Sadakata Masayoshi ; Koshi, Mitsuo. | |
2010-05-11 ; 2010-05-11 | |
关键词 | Theoretical or Mathematical Experimental/ additives air pollution control environmental factors flue gas desulphurisation free radical reactions nitrogen compounds optimisation oxidation sulphur compounds/ dry flue gas desulfurization technique radical chain reactions peroxide test hydrocarbon test nitric acid test additives OH radicals oxidation optimization SO/sub 2/ NO/ A8670L Measurement techniques and instrumentation in environmental science A8230S Chain reactions A8230C Atom and radical reactions (with themselves or with molecules) A8670G Atmosphere (environmental science) E0230 Environmental issues E0210G Optimisation/ SO2/bin O2/bin O/bin S/bin NO/bin N/bin O/bin |
中文摘要 | A method was developed to simultaneously oxidize NO and SO/sub 2 / through radical chain reactions to improve dry flue gas desulfurization technique. The mechanism was analyzed and adding additives was suggested to initiate the chain reactions in the flue gas. Peroxide, hydrocarbons, and nitric acid were tested as additives by experiments, respectively. The results show that NO and SO/sub 2/ can be simultaneously oxidized in flue gas by the chain reactions with appropriate additives. Peroxide and the hydrocarbons fail to sustain the chain reactions due to their own consumption of OH radicals. Nitric acid efficiently provides OH radicals to promote the simultaneous oxidation of NO and SO/sub 2/. Optimization of the reaction conditions favors the oxidation of NO and SO/sub 2/. |
语种 | 中文 ; 中文 |
出版者 | Tsinghua Univ. Press ; China |
内容类型 | 期刊论文 |
源URL | [http://hdl.handle.net/123456789/25870] |
专题 | 清华大学 |
推荐引用方式 GB/T 7714 | Song Qiang,Sadakata Masayoshi,Koshi, Mitsuo.. An improved dry flue gas desulfurization technique through radical chain reactions[J],2010, 2010. |
APA | Song Qiang,Sadakata Masayoshi,&Koshi, Mitsuo..(2010).An improved dry flue gas desulfurization technique through radical chain reactions.. |
MLA | Song Qiang,et al."An improved dry flue gas desulfurization technique through radical chain reactions".(2010). |
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