Bis(crown-6)calix[4]arene/Cs+ coordination chemistry in NPME solution | |
Gao, JX ; Wang, JC ; Song, CL ; Liu, T ; Hu, TD ; Xie, YN ; Zhang, J ; Wang, G ; Yang, H | |
2010-05-10 ; 2010-05-10 | |
关键词 | bis(C6) NPME AXFS NMR spectroscopy coordination chemistry crown ether SUPPORTED LIQUID MEMBRANES 1,3-ALTERNATE CONFORMATION MOLECULAR-DYNAMICS CESIUM COMPLEXES SODIUM EXTRACTION SIMULATION TRANSPORT CRYSTAL Chemistry, Physical |
中文摘要 | NMR spectroscopy was used to show that the symmetry of the crown ether bis(C6) is increased by an increase of the alkali metal cation radius. The EXAFS spectrum demonstrates that a seven oxygen atom coordinated configuration is present in the bis(C6)/Cs+/NPME system, where NPME denotes o-nitrophenylmethyl ether. The seventh oxygen in this complex, besides the six crown ether oxygens of bis(C6), may come either from a H2O molecule or an NO3- ion. |
语种 | 英语 ; 英语 |
出版者 | SPRINGER/PLENUM PUBLISHERS ; NEW YORK ; 233 SPRING ST, NEW YORK, NY 10013 USA |
内容类型 | 期刊论文 |
源URL | [http://hdl.handle.net/123456789/23074] |
专题 | 清华大学 |
推荐引用方式 GB/T 7714 | Gao, JX,Wang, JC,Song, CL,et al. Bis(crown-6)calix[4]arene/Cs+ coordination chemistry in NPME solution[J],2010, 2010. |
APA | Gao, JX.,Wang, JC.,Song, CL.,Liu, T.,Hu, TD.,...&Yang, H.(2010).Bis(crown-6)calix[4]arene/Cs+ coordination chemistry in NPME solution.. |
MLA | Gao, JX,et al."Bis(crown-6)calix[4]arene/Cs+ coordination chemistry in NPME solution".(2010). |
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