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Bis(crown-6)calix[4]arene/Cs+ coordination chemistry in NPME solution
Gao, JX ; Wang, JC ; Song, CL ; Liu, T ; Hu, TD ; Xie, YN ; Zhang, J ; Wang, G ; Yang, H
2010-05-10 ; 2010-05-10
关键词bis(C6) NPME AXFS NMR spectroscopy coordination chemistry crown ether SUPPORTED LIQUID MEMBRANES 1,3-ALTERNATE CONFORMATION MOLECULAR-DYNAMICS CESIUM COMPLEXES SODIUM EXTRACTION SIMULATION TRANSPORT CRYSTAL Chemistry, Physical
中文摘要NMR spectroscopy was used to show that the symmetry of the crown ether bis(C6) is increased by an increase of the alkali metal cation radius. The EXAFS spectrum demonstrates that a seven oxygen atom coordinated configuration is present in the bis(C6)/Cs+/NPME system, where NPME denotes o-nitrophenylmethyl ether. The seventh oxygen in this complex, besides the six crown ether oxygens of bis(C6), may come either from a H2O molecule or an NO3- ion.
语种英语 ; 英语
出版者SPRINGER/PLENUM PUBLISHERS ; NEW YORK ; 233 SPRING ST, NEW YORK, NY 10013 USA
内容类型期刊论文
源URL[http://hdl.handle.net/123456789/23074]  
专题清华大学
推荐引用方式
GB/T 7714
Gao, JX,Wang, JC,Song, CL,et al. Bis(crown-6)calix[4]arene/Cs+ coordination chemistry in NPME solution[J],2010, 2010.
APA Gao, JX.,Wang, JC.,Song, CL.,Liu, T.,Hu, TD.,...&Yang, H.(2010).Bis(crown-6)calix[4]arene/Cs+ coordination chemistry in NPME solution..
MLA Gao, JX,et al."Bis(crown-6)calix[4]arene/Cs+ coordination chemistry in NPME solution".(2010).
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