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Synthesis and electrochemical properties of a LiNi /sub 0.7/Co/sub 0.3/O/sub 1.9/Cl/sub 0.1/ cathode material for lithium-ion battery
Xinlu Li ; Feiyu Kang ; Yongping Zheng ; Xiujuan Shi ; Wanci Shen
2010-05-10 ; 2010-05-10
关键词Experimental/ cathodes electrochemical electrodes lithium compounds materials preparation powders secondary cells voltammetry (chemical analysis) X-ray diffraction/ electrochemical property cathode material lithium-ion battery phase structure X-ray diffraction discharge capacity constant current charge-discharge experiments cyclic voltammograms reversible capacity cycle stability 2.5 to 4.3 V LiNi /sub 0.7/Co/sub 0.3/O/sub 1.9/Cl/sub 0.1/ LiNi/sub 0.7/Co/sub 0.3/O/sub 2// A8245 Electrochemistry and electrophoresis A8120E Powder techniques, compaction and sintering A8140R Electrical and magnetic properties (related to treatment conditions) A6140G Structure of powders and porous materials A8280F Electrochemical analytical methods A8630F Secondary cells B8410E Secondary cells/ voltage 2.5E+00 to 4.3E+00 V/ LiNi0.7Co0.3O2/ss Co0.3/ss Ni0.7/ss O2/ss Co/ss Li/ss Ni/ss O/ss LiNi0.7Co0.3O1.9Cl0.1/ss Cl0.1/ss Co0.3/ss Ni0.7/ss O1.9/ss Cl/ss Co/ss Li/ss Ni/ss O/ss
中文摘要Partial oxygen in LiNi/sub 0.7/Co/sub 0.3/O/sub 2/ was replaced by chlorine to form LiNi /sub 0.7/Co/sub 0.3/O/sub 1.9/Cl/sub 0.1/. Phase structure of LiNi /sub 0.7/Co/sub 0.3/O/sub 1.9/Cl/sub 0.1/ was identified as a pure hexagonal lattice of alpha -NaFeO/sub 2/ type by X-ray diffraction. Discharge capacity of LiNi /sub 0.7/Co/sub 0.3/O/sub 1.9/Cl/sub 0.1/ was 202 mAh/g in initial cycle at 15 mA/g current density in 2.5-4.3 V potential window. The constant current charge/discharge experiments and cyclic voltammograms showed that chlorine addition was effective to improve reversible capacity and cycle stability of LiNi/sub 0.7/Co/sub 0.3/O/sub 2/.
语种英语 ; 英语
出版者Trans Tech Publications ; Switzerland
内容类型期刊论文
源URL[http://hdl.handle.net/123456789/21520]  
专题清华大学
推荐引用方式
GB/T 7714
Xinlu Li,Feiyu Kang,Yongping Zheng,et al. Synthesis and electrochemical properties of a LiNi /sub 0.7/Co/sub 0.3/O/sub 1.9/Cl/sub 0.1/ cathode material for lithium-ion battery[J],2010, 2010.
APA Xinlu Li,Feiyu Kang,Yongping Zheng,Xiujuan Shi,&Wanci Shen.(2010).Synthesis and electrochemical properties of a LiNi /sub 0.7/Co/sub 0.3/O/sub 1.9/Cl/sub 0.1/ cathode material for lithium-ion battery..
MLA Xinlu Li,et al."Synthesis and electrochemical properties of a LiNi /sub 0.7/Co/sub 0.3/O/sub 1.9/Cl/sub 0.1/ cathode material for lithium-ion battery".(2010).
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