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	Hydrothermal synthesis and crystal structure of a novel 2-D polymeric manganese (II) complex with mixed ligands
	Yao, YW ; Lin, HX ; Sun, XD ; Kou, HZ ; Cai, Q ; Li, HD ; Yu, RB ; Wang, D
	2010-05-10 ; 2010-05-10
关键词	ONE-DIMENSIONAL CHAIN COORDINATION POLYMERS MAGNETIC-PROPERTIES ACID MONONUCLEAR FRAMEWORKS BONDS SALTS ZINC Chemistry, Inorganic & Nuclear
中文摘要	A novel polymeric complex, [Mn(phen)(pdc)](infinity) ( phen 1,10- phenanthroline, H(2)pdc 2,5-pyridinedicarboxylic acid) has been synthesized from the hydrothermal reaction system of H2pdc, phen, MnO2, and H2O. [Mn(phen)(pdc)](infinity) is characteristic of an edge-sharing dinuclear Mn-II structure unit bridged by pdc, leading to a 2-D framework whose stacking is based on weak H-bond interaction. The temperature dependence of the magnetic susceptibility for [Mn(phen)( pdc)](infinity) indicates antiferromagnetic coupling [J= -2.76(4)cm(-1)] between the adjacent paramagnetic Mn-II ions.
语种	英语 ; 英语
出版者	SPRINGER ; DORDRECHT ; VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS
内容类型	期刊论文
源URL	[http://hdl.handle.net/123456789/21234]
专题	清华大学
推荐引用方式 GB/T 7714	Yao, YW,Lin, HX,Sun, XD,et al. Hydrothermal synthesis and crystal structure of a novel 2-D polymeric manganese (II) complex with mixed ligands[J],2010, 2010.
APA	Yao, YW.,Lin, HX.,Sun, XD.,Kou, HZ.,Cai, Q.,...&Wang, D.(2010).Hydrothermal synthesis and crystal structure of a novel 2-D polymeric manganese (II) complex with mixed ligands..
MLA	Yao, YW,et al."Hydrothermal synthesis and crystal structure of a novel 2-D polymeric manganese (II) complex with mixed ligands".(2010).

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