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Effect of molybdenum ion implantation on corrosion resistance of zircaloy-4
Peng Dequan ; Bai Xinde ; Zhou Qinggang ; Liu Xiaoyang ; Yu Renhong
2010-05-10 ; 2010-05-10
关键词Experimental/ corrosion resistance ion implantation molybdenum scanning electron microscopy surface morphology valency X-ray photoelectron spectra zirconium alloys/ molybdenum ion implantation zircaloy-4 valence surface layer X-ray electron spectroscopy XPS three-sweep potentiodynamic polarization measurement aqueous corrosion resistance H/sub 2/SO/sub 4/ solution scanning electron microscopy SEM surface morphology molybdenum-implanted zirconium/ A8160B Surface treatment and degradation of metals and alloys A6170T Doping and implantation of impurities A6180J Ion beam effects A7960 Photoemission and photoelectron spectra (condensed matter) A6820 Solid surface structure/ Mo/sur Zr/sur Mo/ss Zr/ss Mo/el Mo/dop
中文摘要In order to study the effect of molybdenum ion implantation on the aqueous corrosion behavior of zircaloy-4, specimens were implanted by molybdenum ions with fluence range of 1 * 10/sup 16/ - 1 * 10/sup 17/ cm/sup -2/. The valence of the surface layer was analyzed by X-ray electron spectroscopy (XPS) and the three-sweep potentiodynamic polarization measurement was employed to evaluate the aqueous corrosion resistance of zirconium in 1 mol middot L/sup -1/ H/sub 2/SO/sub 4/ solution. Scanning electron microscopy (SEM) was used to observe the surface morphology of the three-sweep potentiodynamic polarized samples. It was found that a significant improvement was achieved in the aqueous corrosion behavior of zircaloy-4 implanted with molybdenum ions when the fluence was smaller than 5 * 10/sup 16/ cm/sup -2/. When the fluence was higher than 1 * 10/sup 17/ cm/sup -2/, the corrosion resistance of zircaloy-4 implanted with molybdenum ions decreased as compared with that of the as-received zircaloy-4. Finally, the mechanism of the corrosion resistance improvement of the molybdenum-implanted zirconium was discussed.
语种中文 ; 中文
出版者Science Press ; China
内容类型期刊论文
源URL[http://hdl.handle.net/123456789/20488]  
专题清华大学
推荐引用方式
GB/T 7714
Peng Dequan,Bai Xinde,Zhou Qinggang,et al. Effect of molybdenum ion implantation on corrosion resistance of zircaloy-4[J],2010, 2010.
APA Peng Dequan,Bai Xinde,Zhou Qinggang,Liu Xiaoyang,&Yu Renhong.(2010).Effect of molybdenum ion implantation on corrosion resistance of zircaloy-4..
MLA Peng Dequan,et al."Effect of molybdenum ion implantation on corrosion resistance of zircaloy-4".(2010).
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