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Chemical modification of soybean oil for lubricant
Duan Shijie ; Mao Zongqiang
2010-05-10 ; 2010-05-10
会议名称PROCEEDINGS OF ISES SOLAR WORLD CONGRESS 2007: SOLAR ENERGY AND HUMAN SETTLEMENT, VOLS I-V ; Solar World Congress of the International-Solar-Energy-Society ; Beijing, PEOPLES R CHINA ; Web of Science ; INSPEC
关键词Construction & Building Technology Energy & Fuels Materials Science, Coatings & Films
中文摘要This paper presents a series of structural modifications of soybean oils for lubricant. The reaction was monitored and products were confirmed by NMR and FTIR. The structural modification is carried out in four stages, (I)synthesis of soybean oil isooctyl ester from soybean oil; (2) synthesis of epoxy-soybean oil isooctyl ester from soybean oil isooctyl ester;(3)synthesis of hydroxylated products from epoxy soybean oil isooctyl ester with fatty acid; (4) esterification of the hydroxylated product with anhydride. Rheological behaviour of the products was measured. Pour points of the products (3) were observed as low as -24 degrees C (lauric acid) and -15 degrees C (isooctanoic acid) respectively. When the hydroxyl groups in the products were esterified with and acid anhydride, the pour points were became higher, which were -21 degrees C (lauric acid) and -6 degrees C (isooctanoic acid) without pour point depr- essant, and -27 degrees C(lauric acid) and-24 degrees C (isooctanoic acid) with 1% of pour point depressant respectively. The products have suitable viscosity and viscosity index, and the viscosity indices are all above 100.
会议录出版者TSINGHUA UNIVERSITY PRESS ; BEIJING ; TSINGHUA UNIVERSITY HAIDIANQU, BEIJING 100084, PEOPLES R CHINA
语种英语 ; 英语
内容类型会议论文
源URL[http://hdl.handle.net/123456789/18834]  
专题清华大学
推荐引用方式
GB/T 7714
Duan Shijie,Mao Zongqiang. Chemical modification of soybean oil for lubricant[C]. 见:PROCEEDINGS OF ISES SOLAR WORLD CONGRESS 2007: SOLAR ENERGY AND HUMAN SETTLEMENT, VOLS I-V, Solar World Congress of the International-Solar-Energy-Society, Beijing, PEOPLES R CHINA, Web of Science, INSPEC.
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