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Investigation on structure and electrochemical properties of Li[Ni1/3Co1/3Mn1/3]O-2 for lithium ion batteries
Shi, Xiujuan ; Zheng, Yongping ; Kang, Feiyu ; Li, Xinlu ; Shen, Wanci
2010-05-10 ; 2010-05-10 ; OCT 23-26, 2005
会议名称High-Performance Ceramics IV, Pts 1-3 ; 4th China International Conference on High-Performance Ceramics (CICC-4) ; Chengdu, PEOPLES R CHINA ; Web of Science
关键词Li[Ni1/3Co1/3Mn1/3]O-2 cathode material lithium-ion batteries Materials Science, Ceramics Materials Science, Composites
中文摘要Cathode material Li[Ni1/3Co1/3Mn1/3]O-2 for lithium-ion batteries with layered hexagonal structure was successfully synthesized in sol-gel way. The influences of calcination temperature (from 700 degrees to 1000 degrees C) on the structure and electrochemical behaviors of Li[Ni1/3Co1/3Mn1/3]O-2 were extensively investigated. The results of XRD show that all samples are isostructural with alpha-NaFeO2 with a space group R-3m. XPS analysis shows that the oxidation states of Co and Mn were Co3+ and Mn4+ respectively, while Ni exists as Ni2+ and Ni3+. The charge-discharge experiments show that the sample calcined at 850 degrees C delivers 194.8mAh/g in the first cycle at C/5 rate in 2.5-4.3V potential range.
会议录出版者TRANS TECH PUBLICATIONS LTD ; STAFA-ZURICH ; LAUBLSRUTISTR 24, CH-8717 STAFA-ZURICH, SWITZERLAND
语种英语 ; 英语
内容类型会议论文
源URL[http://hdl.handle.net/123456789/18052]  
专题清华大学
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GB/T 7714
Shi, Xiujuan,Zheng, Yongping,Kang, Feiyu,et al. Investigation on structure and electrochemical properties of Li[Ni1/3Co1/3Mn1/3]O-2 for lithium ion batteries[C]. 见:High-Performance Ceramics IV, Pts 1-3, 4th China International Conference on High-Performance Ceramics (CICC-4), Chengdu, PEOPLES R CHINA, Web of Science.
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