Numerical simulation of substrate effects on spinodal decomposition in polymer binary mixture: Effects of the surface potential | |
Yan, Li-Tang ; Xie, Xu-Ming | |
2010-05-07 ; 2010-05-07 | |
关键词 | substrate effect spinodal decomposition cell dynamic system simulation PHASE-SEPARATION DYNAMICS LIQUID-CRYSTALLINE COPOLYESTER QUENCH DEPTH DEPENDENCE STEADY SHEAR-FLOW THIN-FILMS GRADIENT MORPHOLOGY DIBLOCK COPOLYMERS PATTERNED SURFACES BLEND FILMS KINETICS Polymer Science |
中文摘要 | The surface-directed spinodall decomposition (SDSD) of polymer binary mixture with different values of surface potential is numerically simulated in three-dimension (3D) by cell dynamic systems (CDS). Furthermore, the growth laws of the wetting layer are theoretically analyzed by the current equation and the dynamical scaling. The results show that the thickness of the wetting layer increases with the increasing surface potential. The crossover, which is later for larger values of surface potential, appears in the evolution curve of the wetting layer. Before the crossover, the growth law is the surface potential dependant growth law. Subsequently, the growth law is the typical Lifshitz-Slyozov (LS) growth law. The results indicate that the surface potential can result in the mutual transformation between completely wetting and partially wetting for the substrate interface. It can be found that the higher surface potential leads to the faster and stronger transmission of the effect of the substrate on the spinodal decomposition in the bulk. (c) 2006 Elsevier Ltd. All rights reserved. |
语种 | 英语 ; 英语 |
出版者 | ELSEVIER SCI LTD ; OXFORD ; THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND |
内容类型 | 期刊论文 |
源URL | [http://hdl.handle.net/123456789/17394] ![]() |
专题 | 清华大学 |
推荐引用方式 GB/T 7714 | Yan, Li-Tang,Xie, Xu-Ming. Numerical simulation of substrate effects on spinodal decomposition in polymer binary mixture: Effects of the surface potential[J],2010, 2010. |
APA | Yan, Li-Tang,&Xie, Xu-Ming.(2010).Numerical simulation of substrate effects on spinodal decomposition in polymer binary mixture: Effects of the surface potential.. |
MLA | Yan, Li-Tang,et al."Numerical simulation of substrate effects on spinodal decomposition in polymer binary mixture: Effects of the surface potential".(2010). |
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