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Explorations on growth mechanism, controlled synthesis and applications of carbon nanotubes
Fan Shou-Shan ; Jiang Kai-Li ; Liu Liang ; Liu Chang-Hong ; Li Qun-Qing
2010-05-06 ; 2010-05-06
关键词Experimental/ carbon nanotubes chemical vapour deposition etching extrusion interface phenomena nanotechnology thermal conductivity yarn/ growth mechanism controlled synthesis carbon nanotubes macroscopic structures /sup 13/C labeling method chemical vapor deposition CVD extrusion model reactive gas flow rate super-aligned CNT arrays wafer scale CNT yarn volatile organic solvents thermal electron sources current density field emitters fluorescent tubes thermal interface materials IT industry CNT array-polymer matrix thermal conductivity thermal resistance tip etching surface metal layer/ A8116 Methods of nanofabrication and processing A8115H Chemical vapour deposition A6148 Structure of fullerenes and fullerene-related materials A6865 Low-dimensional structures: growth, structure and nonelectronic properties A6670 Nonelectronic thermal conduction and heat-pulse propagation in nonmetallic solids A8160 Corrosion, oxidation, etching, and other surface treatments
中文摘要Controlled synthesis of carbon nanotubes (CNTs) and assembling them into macroscopic structures are of great importance to the applications of carbon nanotubes, and a deep understanding of the growth mechanism of carbon nanotubes would be an indispensable prerequisite for well-defined synthesis in a controllable way. Here we show some of our recent progress in carbon nanotubes growth mechanism, controlled synthesis, and applications. By introducing a /sup 13/C labeling method, we revealed that the growth mechanism of the carbon nanotubes made by chemical vapor deposition (CVD) is the "extrusion model". Serials of labels can be embedded into CNTs by tuning the composition and the flow rate of the reactive gases during the growth process, and the growth rate of CNT arrays can be calculated thereby. The fabrication of super-aligned CNT arrays was expanded to 4-inch wafer scale. A novel method was invented to process the raw yarn by passing through volatile organic solvents. As a result, both the strength and manipulability were improved substantially. The processed yarn can be applied as thermal electron sources, large current density field emitters and in fluorescent tubes etc. Thermal interface materials (TIMs) has significant importance in IT industry, we prepared CNT array-polymer matrix which has very high thermal conductivity and extremely low thermal resistance. Techniques like chemical modification, tip etching and surface metal layer were explored to enhance the thermal conductivity of the CNT thermal interface materials.
语种中文 ; 中文
出版者Chinese Phys. Soc ; China
内容类型期刊论文
源URL[http://hdl.handle.net/123456789/14827]  
专题清华大学
推荐引用方式
GB/T 7714
Fan Shou-Shan,Jiang Kai-Li,Liu Liang,et al. Explorations on growth mechanism, controlled synthesis and applications of carbon nanotubes[J],2010, 2010.
APA Fan Shou-Shan,Jiang Kai-Li,Liu Liang,Liu Chang-Hong,&Li Qun-Qing.(2010).Explorations on growth mechanism, controlled synthesis and applications of carbon nanotubes..
MLA Fan Shou-Shan,et al."Explorations on growth mechanism, controlled synthesis and applications of carbon nanotubes".(2010).
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