An electron momentum spectroscopy investigation on the 1a' inner valence orbital of cyclopentene | |
Su, GL ; Ren, XG ; Zhang, SF ; Ning, CG ; Zhou, H ; Li, B ; Huang, F ; Li, GQ ; Deng, JK | |
2010-05-06 ; 2010-05-06 | |
关键词 | cyclopentene inner valence orbital ionization energy electron momentum profiles electron correlation effects E,2E SPECTROSCOPY MOLECULES DIACETYL Physics, Multidisciplinary |
中文摘要 | The ionization energy spectrum and the spherically averaged momentum distribution of 1a' inner valance orbital for cyclopentene have been investigated by using a high resolution ( Delta E = 1.15 eV, Delta p approximate to 0.1 a.u.) electron momentum spectrometer. The impact energy was 1200eV plus binding energy ( i.e. 1202-1234eV) and a symmetric non-coplanar kinematics was employed. The experimental momentum profile of the 1a' inner valence orbital is obtained and compared with the theoretical momentum distributions calculated by using Hartree-Fock and density functional theory methods with the basis sets STO-3G, 6-31G, 6-311 + + G* * and aug-cc-pVTZ. The pole strength of the 1a' inner valence orbital is estimated and the electron correlation effects are discussed. |
语种 | 中文 ; 中文 |
出版者 | CHINESE PHYSICAL SOC ; BEIJING ; P O BOX 603, BEIJING 100080, PEOPLES R CHINA |
内容类型 | 期刊论文 |
源URL | [http://hdl.handle.net/123456789/14451] ![]() |
专题 | 清华大学 |
推荐引用方式 GB/T 7714 | Su, GL,Ren, XG,Zhang, SF,et al. An electron momentum spectroscopy investigation on the 1a' inner valence orbital of cyclopentene[J],2010, 2010. |
APA | Su, GL.,Ren, XG.,Zhang, SF.,Ning, CG.,Zhou, H.,...&Deng, JK.(2010).An electron momentum spectroscopy investigation on the 1a' inner valence orbital of cyclopentene.. |
MLA | Su, GL,et al."An electron momentum spectroscopy investigation on the 1a' inner valence orbital of cyclopentene".(2010). |
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