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	Synergetic degradation of rhodamine B at a porous ZnWO4 film electrode by combined electro-oxidation and photocatalysis
	Zhao, X ; Zhu, YF
	2010-05-06 ; 2010-05-06
关键词	WASTE-WATER TREATMENT ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY VISIBLE-LIGHT IRRADIATION FORMIC-ACID PHOTOELECTROCATALYTIC DEGRADATION PHOTOELECTROCHEMICAL DEGRADATION OXIDE ELECTRODES ANODIC-OXIDATION AQUEOUS-SOLUTION TIO2 Engineering, Environmental Environmental Sciences
中文摘要	Synergetic degradation of rhodamine B (RhB) was investigated by combining electro-oxidation and photocatalysis using porous ZnWO4 film at various bias potentials. The applied bias potential below 0.8 V enhanced the photocatalytic degradation of RhB by promoting the separation and transfer of photogenerated holes and electrons. At the potential between 0.8 and 1.0 V, the degradation of RhB was further enhanced, which is induced by direct electrooxidation and photocatalysis. At the potential greater than 1.3 V, indirect electro-oxidation of RhB occurred with the largest synergetic effect. The synergetic effect can also increase the mineralization degree of the RhB. On the basis of the X-ray photoelectron spectra (XPS) analysis of the surface of the electrode after electrochemical reaction, the electropolymerization occurred which blocked the electrode and slowed the electro-oxidation of RhB. Active species generated via the photocatalytic process can activate the passivated electrode and promote the electrooxidation of RhB. The O-2 electrochemically generated at the anode promoted the photocatalysis by capturing the photogenerated electrons and may induce the formation of H2O2. Thus, more active species could be formed through new reactive routines in the photoelectrocatalytic (PEC) process. RhB degradation was mainly through decomposition of the conjugated chromophore structure with slight occurrence of de-ethylation. The stability of the electrode in the PEC process was confirmed based on the XPS and Raman analysis.
语种	英语 ; 英语
出版者	AMER CHEMICAL SOC ; WASHINGTON ; 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
内容类型	期刊论文
源URL	[http://hdl.handle.net/123456789/13425]
专题	清华大学
推荐引用方式 GB/T 7714	Zhao, X,Zhu, YF. Synergetic degradation of rhodamine B at a porous ZnWO4 film electrode by combined electro-oxidation and photocatalysis[J],2010, 2010.
APA	Zhao, X,&Zhu, YF.(2010).Synergetic degradation of rhodamine B at a porous ZnWO4 film electrode by combined electro-oxidation and photocatalysis..
MLA	Zhao, X,et al."Synergetic degradation of rhodamine B at a porous ZnWO4 film electrode by combined electro-oxidation and photocatalysis".(2010).

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