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Raman spectroscopic study on the chain conformation of electrosynthesized poly(p-phenylene) films
Chen, FE ; Fu, MX ; Wang, F ; Fan, B ; Shi, GQ
2010-05-06 ; 2010-05-06
关键词poly(p-phenylene) Raman spectroscopy conformation TRIFLUORIDE DIETHYL ETHERATE CONDUCTING POLYMERS ELECTROCHEMICAL POLYMERIZATION POLY(3-METHYLTHIOPHENE) POLY(PARA-PHENYLENE) SPECTRA Polymer Science
中文摘要Poly(p-phenylene) (PPP) films have been electrochemically deposited on mirrorlike stainless steel (SS) electrode surfaces by direct oxidation of benzene in boron trifluoride diethyl etherate (BFEE) solutions at a constant applied potential of 1.7 V (versus Ag/AgCl). The chain conformations of as-grown PPP films have been studied by Raman spectroscopy. The results demonstrated that high synthesis temperature favors the formation of planar PPP, and the conformation of planar PPP can be changed into torsional PPP by cooling treatment.
语种英语 ; 英语
出版者WORLD SCIENTIFIC PUBL CO PTE LTD ; SINGAPORE ; 5 TOH TUCK LINK, SINGAPORE 596224, SINGAPORE
内容类型期刊论文
源URL[http://hdl.handle.net/123456789/12901]  
专题清华大学
推荐引用方式
GB/T 7714
Chen, FE,Fu, MX,Wang, F,et al. Raman spectroscopic study on the chain conformation of electrosynthesized poly(p-phenylene) films[J],2010, 2010.
APA Chen, FE,Fu, MX,Wang, F,Fan, B,&Shi, GQ.(2010).Raman spectroscopic study on the chain conformation of electrosynthesized poly(p-phenylene) films..
MLA Chen, FE,et al."Raman spectroscopic study on the chain conformation of electrosynthesized poly(p-phenylene) films".(2010).
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