Copper-catalyzed amidation of Sp(3) C-H bonds adjacent to a nitrogen atom | |
Zhang, Yongming ; Fu, Hua ; Jiang, Yuyang ; Zhao, Yufen | |
2010-05-06 ; 2010-05-06 | |
关键词 | CARBON-HYDROGEN BONDS INTRAMOLECULAR AMIDATION FUNCTIONALIZATION ACTIVATION AZIRIDINATION ALKYNYLATION PORPHYRINS AMINATION OXIDATION INSERTION Chemistry, Organic |
中文摘要 | We have developed a novel copper-catalyzed amidation of unactivated sp(3) C-H bonds adjacent to a nitrogen atom by using an inexpensive catalyst-oxidant (CuBr/(BuOOH)-Bu-t) system under mild conditions. The dephenylation was first found for N-benzylaniline, and the new class of products provide diverse structures for pharmaceuticals and combinatorial chemistry. |
语种 | 英语 ; 英语 |
出版者 | AMER CHEMICAL SOC ; WASHINGTON ; 1155 16TH ST, NW, WASHINGTON, DC 20036 USA |
内容类型 | 期刊论文 |
源URL | [http://hdl.handle.net/123456789/12766] ![]() |
专题 | 清华大学 |
推荐引用方式 GB/T 7714 | Zhang, Yongming,Fu, Hua,Jiang, Yuyang,et al. Copper-catalyzed amidation of Sp(3) C-H bonds adjacent to a nitrogen atom[J],2010, 2010. |
APA | Zhang, Yongming,Fu, Hua,Jiang, Yuyang,&Zhao, Yufen.(2010).Copper-catalyzed amidation of Sp(3) C-H bonds adjacent to a nitrogen atom.. |
MLA | Zhang, Yongming,et al."Copper-catalyzed amidation of Sp(3) C-H bonds adjacent to a nitrogen atom".(2010). |
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