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	A cyano-bridged trimeric complex [Mn(CH3OH)(2)(H2O)(2)][Fe(bpb)(CN)(2)](2)center dot 2H(2)O [bpb(2-) is 1,2-bis(pyridine-2-carboxamido)benzenate]
	Ni, ZH ; Kou, HZ ; Zhang, LF ; Jiang, YB ; Cui, AL
	2010-05-06 ; 2010-05-06
关键词	VERSATILE BUILDING-BLOCK MAGNETIC-PROPERTIES CRYSTAL-STRUCTURES CLUSTERS SYSTEMS DESIGN CAGE Crystallography
中文摘要	The structure of the title complex, diaquadi-mu-cyano-dicyanodimethanolbis[N,N'-o-phenylenebis(pyridine-2-carboxamidato)] diiron(III) manganese(II), [MnFe2(C18H12N4O2)(2)(CN)(4)(CH4O)(2)(H2O)(2)]center dot 2H(2)O, consists of neutral centrosymmetric [Mn(CH3OH)(2)(H2O)(2)][Fe(bpb)(CN)(2)](2) heterotrinuclear units [bpb(2-)=1,2-bis(pyridine-2-carboxamido) benzene(2-)] and water molecules of crystallization. Each [Fe(bpb)(CN)(2)](-) unit acts as a monodentate ligand through one of its two cyanide groups toward the central Mn-II ion (site symmetry (1) over bar) in a bent fashion [C-N-Mn=159.7 (2)degrees].
语种	英语 ; 英语
出版者	BLACKWELL MUNKSGAARD ; FREDERIKSBERG C ; 1 ROSENORNS ALLE, DK-1970 FREDERIKSBERG C, DENMARK
内容类型	期刊论文
源URL	[http://hdl.handle.net/123456789/12656]
专题	清华大学
推荐引用方式 GB/T 7714	Ni, ZH,Kou, HZ,Zhang, LF,et al. A cyano-bridged trimeric complex [Mn(CH3OH)(2)(H2O)(2)][Fe(bpb)(CN)(2)](2)center dot 2H(2)O [bpb(2-) is 1,2-bis(pyridine-2-carboxamido)benzenate][J],2010, 2010.
APA	Ni, ZH,Kou, HZ,Zhang, LF,Jiang, YB,&Cui, AL.(2010).A cyano-bridged trimeric complex [Mn(CH3OH)(2)(H2O)(2)][Fe(bpb)(CN)(2)](2)center dot 2H(2)O [bpb(2-) is 1,2-bis(pyridine-2-carboxamido)benzenate]..
MLA	Ni, ZH,et al."A cyano-bridged trimeric complex [Mn(CH3OH)(2)(H2O)(2)][Fe(bpb)(CN)(2)](2)center dot 2H(2)O [bpb(2-) is 1,2-bis(pyridine-2-carboxamido)benzenate]".(2010).

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