A novel one-dimensional complex: catena-poly[[manganese(III)-di-mu-2-[(2-hydroxyethyl)iminomethyl]-phenolato-kappa O-2(1),N :kappa O-2;kappa O-2 :kappa O-2] chloride] | |
Zhang, LF ; Ni, ZH ; Zong, ZM ; Wei, XY ; Ge, CH ; Kou, HZ | |
2010-05-06 ; 2010-05-06 | |
关键词 | SINGLE-MOLECULE MAGNET DINUCLEAR PHENOXO LIGANDS BRIDGES FAMILY CUBES WHEEL Crystallography |
中文摘要 | In the title one-dimensional complex, {[Mn-III(C9H10NO2)(2)]Cl}(n), the Schiff base ligand 2-[(2-hydroxyethyl) iminomethyl]phenolate (Hsae(-)) functions as both a bridging and a chelating ligand. The Mn-III ion is six-coordinated by two N and four O atoms from four different Hsae(-) ligands, yielding a distorted MnO4N2 octahedral environment. Each [Mn-III( Hsae)(2)](+) cationic unit has the Mn atom on an inversion centre and each [Mn-III(Hsae)(2)](+) cation lies about another inversion centre. The chain-like complex is further extended into a three-dimensional network structure through Cl center dot center dot center dot H-O hydrogen bonds and C - H center dot center dot center dot pi contacts involving the Hsae. rings. |
语种 | 英语 ; 英语 |
出版者 | BLACKWELL PUBLISHING ; OXFORD ; 9600 GARSINGTON RD, OXFORD OX4 2DQ, OXON, ENGLAND |
内容类型 | 期刊论文 |
源URL | [http://hdl.handle.net/123456789/12266] ![]() |
专题 | 清华大学 |
推荐引用方式 GB/T 7714 | Zhang, LF,Ni, ZH,Zong, ZM,et al. A novel one-dimensional complex: catena-poly[[manganese(III)-di-mu-2-[(2-hydroxyethyl)iminomethyl]-phenolato-kappa O-2(1),N :kappa O-2;kappa O-2 :kappa O-2] chloride][J],2010, 2010. |
APA | Zhang, LF,Ni, ZH,Zong, ZM,Wei, XY,Ge, CH,&Kou, HZ.(2010).A novel one-dimensional complex: catena-poly[[manganese(III)-di-mu-2-[(2-hydroxyethyl)iminomethyl]-phenolato-kappa O-2(1),N :kappa O-2;kappa O-2 :kappa O-2] chloride].. |
MLA | Zhang, LF,et al."A novel one-dimensional complex: catena-poly[[manganese(III)-di-mu-2-[(2-hydroxyethyl)iminomethyl]-phenolato-kappa O-2(1),N :kappa O-2;kappa O-2 :kappa O-2] chloride]".(2010). |
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