Regioselective Pd-catalyzed indolization of 2-bromoanilines with internal alkynes using phosphine-free ligands | |
Cui, Xin ; Li, Juan ; Fu, Yao ; Liu, Lei ; Guo, Qing-Xiang | |
2010-05-06 ; 2010-05-06 | |
关键词 | indole Larock indolization palladium catalyst phosphine-free ligand heteroannulation CROSS-COUPLING REACTION DIMETHYL-SULFOXIDE SOLUTION ACTIVE PD(II) CATALYSTS HECK REACTION SUZUKI REACTION INDOLE SYNTHESIS ARYL BROMIDES 2,3-DISUBSTITUTED INDOLES PALLADIUM COMPLEX EFFICIENT LIGAND Chemistry, Organic |
中文摘要 | The possibility of using phosphine-free ligands to promote Pd-catalyzed indolization of 2-bromoanilines with internal alkynes was examined for the first time. Phenylurea was found to be the optimal ligand, which could mediate the synthesis of 2,3 -disubstituted indoles in good yields (ca. 60-85%) with high regioselectivity. (C) 2008 Elsevier Ltd. All rights reserved. |
语种 | 英语 ; 英语 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD ; OXFORD ; THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND |
内容类型 | 期刊论文 |
源URL | [http://hdl.handle.net/123456789/12199] ![]() |
专题 | 清华大学 |
推荐引用方式 GB/T 7714 | Cui, Xin,Li, Juan,Fu, Yao,et al. Regioselective Pd-catalyzed indolization of 2-bromoanilines with internal alkynes using phosphine-free ligands[J],2010, 2010. |
APA | Cui, Xin,Li, Juan,Fu, Yao,Liu, Lei,&Guo, Qing-Xiang.(2010).Regioselective Pd-catalyzed indolization of 2-bromoanilines with internal alkynes using phosphine-free ligands.. |
MLA | Cui, Xin,et al."Regioselective Pd-catalyzed indolization of 2-bromoanilines with internal alkynes using phosphine-free ligands".(2010). |
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