The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 中国科学院特殊环境功能材料与器件重点试验室

	The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges
	Mutailipu, M (Mutailipu, Miriding); Zhang, M (Zhang, Min); Chen, YN (Chen, Yanna); Lu, XQ (Lu, Xiaoquan); Pan, SL (Pan, Shilie)
刊名	DALTON TRANSACTIONS
	2017
卷号	46 期号:15 页码:4923-4928
通讯作者	Zhang, M ; Pan, SL
英文摘要	Two new mixed-metal borate halides, namely, NaMg2Ba7B14O28F5 (I) and NaBa4B10O18BrF2 (II), were synthesized using the high-temperature flux method. Both structures were characterized by single-crystal X-ray diffraction, and their structures are shown to feature complicated three dimensional (3D) networks with different types of halogen-centered secondary building units (SBUs). Specifically, compound I contains three spatial fluorine-centered SBUs F(1) Ba4Mg2, F(2) Ba(Na) Ba3Mg, and F(3) Ba(Na) Ba2Mg, while compound II exhibits spatial FBa3Na and planar BrBa4 fluorine-or bromine-centered SBUs. Furthermore, four categories of halogen-centered SBUs were investigated among all the 173 available anhydrous halogen-containing borates to elaborate the role of halogen atoms to enrich the structural diversity of borates. What's more, the crystal structures, thermal stabilities, and UV-Vis-NIR diffuse reflectance spectra of synthesised compounds I and II have also been determined.
收录类别	SCI
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/4766]
专题	新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室新疆理化技术研究所_材料物理与化学研究室
作者单位	1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 2.Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R ChinaBeijing Univ Chem Technol, State Key Lab Chem Resource Engn, North Third Ring Rd 15, Beijing 100029, Peoples R China
推荐引用方式 GB/T 7714	Mutailipu, M ,Zhang, M ,Chen, YN ,et al. The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges[J]. DALTON TRANSACTIONS,2017,46(15):4923-4928.
APA	Mutailipu, M ,Zhang, M ,Chen, YN ,Lu, XQ ,&Pan, SL .(2017).The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges.DALTON TRANSACTIONS,46(15),4923-4928.
MLA	Mutailipu, M ,et al."The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges".DALTON TRANSACTIONS 46.15(2017):4923-4928.