Tandem Spirocyclopropanation/Rearrangement Reaction of Vinyl p-Quinone Methides with Sulfonium Salts: Synthesis of Spirocyclopentenyl p-Dienones
Zhang, Xiang-Zhi1; Deng, Yu-Hua1,3; Gan, Kang-Ji1; Yan, Xu1; Yu, Ke-Yin1; Wang, Fang-Xin1; Fan, Chun-An1,2
刊名Organic Letters
2017
卷号19期号:7页码:1752-1755
ISSN号1523-7060
通讯作者Fan, Chun-An
英文摘要

A novel base-mediated tandem spirocyclopropanation/rearrangement reaction of vinyl p-quinone methides (p-VQMs) with sulfonium salts is described. The unprecedented reactivity of p-VQMs was explored for the first time in the spiroannulation cascade, providing a stereoselective approach to the construction of synthetically interesting, densely functionalized spirocyclopentenyl p-dienones.

学科主题物理化学与绿色催化
收录类别SCI
资助信息NSFC (21572083;21322201;21290180);FRFCU (lzujbky-2015-48;lzujbky-2016-ct02;lzujbky-2016-ct07);PCSIRT (IRT_15R28);the 111 Project of MOE (111-2-17);the Chang Jiang Scholars Program (C.-A.F.)
语种英语
WOS记录号WOS:000398985800066
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/21787]  
专题兰州化学物理研究所_OSSO国家重点实验室
作者单位1.Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, 222 Tianshui Nanlu, Lanzhou 730000, Peoples R China
2.Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China
3.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Xiang-Zhi,Deng, Yu-Hua,Gan, Kang-Ji,et al. Tandem Spirocyclopropanation/Rearrangement Reaction of Vinyl p-Quinone Methides with Sulfonium Salts: Synthesis of Spirocyclopentenyl p-Dienones[J]. Organic Letters,2017,19(7):1752-1755.
APA Zhang, Xiang-Zhi.,Deng, Yu-Hua.,Gan, Kang-Ji.,Yan, Xu.,Yu, Ke-Yin.,...&Fan, Chun-An.(2017).Tandem Spirocyclopropanation/Rearrangement Reaction of Vinyl p-Quinone Methides with Sulfonium Salts: Synthesis of Spirocyclopentenyl p-Dienones.Organic Letters,19(7),1752-1755.
MLA Zhang, Xiang-Zhi,et al."Tandem Spirocyclopropanation/Rearrangement Reaction of Vinyl p-Quinone Methides with Sulfonium Salts: Synthesis of Spirocyclopentenyl p-Dienones".Organic Letters 19.7(2017):1752-1755.
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