Understanding Shale Oil Hydrotreatment with Composition Analysis Using Positive-Ion Mode Atmospheric Pressure Photoionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry

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	Understanding Shale Oil Hydrotreatment with Composition Analysis Using Positive-Ion Mode Atmospheric Pressure Photoionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry
	Zhang, Kui 1,2; Yu, Jian 1; Gao, Shiqiu 1; Li, Changming 1; Xu, Guangwen 1,3
刊名	ENERGY & FUELS
	2017-02-01
卷号	31 期号:2 页码:1362-1369
ISSN号	0887-0624
英文摘要	Positive-ion mode of atmospheric pressure photoionization (APPI) coupled with a 9.4 T Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer has been applied to the characterization of shale oil from pyrolysis and its hydrotreatment. The hydrotreated shale oil was obtained through reactions over catalysts Ni-Mo, Ni-W, or Co-Mo. It was found that N-1 and N1O1 species are the dominant N compounds and Si species is the dominant S compound in shale oil from pyrolyzing Huadian oil shale. The primary aromatic hydrocarbons (AHCs) are mono- and double-ring aromatics. After hydrotreatment, both S and N compounds are effectively removed and the catalyst Ni-Mo shows the best performance in hydrodesulfurization (HDS) and hydrodenitrogenation (HDN). The AHC species, especially the mono-ring aromatics, increases as a result of the transformation of N-1, N1O1, and S-1 species into AHC species through hydrotreatment. Indole, carbazole, acridine, and their derivatives are preserved as N-1 species. The reactions of HDN for shale oil were further analyzed by considering the transformation between N1O1 and N-1 species.
WOS标题词	Science & Technology ; Technology
类目[WOS]	Energy & Fuels ; Engineering, Chemical
研究领域[WOS]	Energy & Fuels ; Engineering
关键词[WOS]	ELECTROSPRAY-IONIZATION ESI ; S-ALKYLSULFONIUM SALTS ; FT-ICR MS ; NITROGEN-COMPOUNDS ; CRUDE-OIL ; SUBSEQUENT PRECIPITATION ; DESULFURIZATION PROCESS ; CONTAINING AROMATICS ; HEAVY PETROLEUM ; LIGHT OIL
收录类别	SCI
语种	英语
WOS记录号	WOS:000394560900032
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/22075]
专题	过程工程研究所_多相复杂系统国家重点实验室
作者单位	1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chem Ind Co Ltd, Southwest Res & Design Inst, Chengdu 610225, Sichuan, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Kui,Yu, Jian,Gao, Shiqiu,et al. Understanding Shale Oil Hydrotreatment with Composition Analysis Using Positive-Ion Mode Atmospheric Pressure Photoionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry[J]. ENERGY & FUELS,2017,31(2):1362-1369.
APA	Zhang, Kui,Yu, Jian,Gao, Shiqiu,Li, Changming,&Xu, Guangwen.(2017).Understanding Shale Oil Hydrotreatment with Composition Analysis Using Positive-Ion Mode Atmospheric Pressure Photoionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry.ENERGY & FUELS,31(2),1362-1369.
MLA	Zhang, Kui,et al."Understanding Shale Oil Hydrotreatment with Composition Analysis Using Positive-Ion Mode Atmospheric Pressure Photoionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry".ENERGY & FUELS 31.2(2017):1362-1369.