Induced anisotropic behavior and enhanced electrical properties on hot-pressed strontium barium niobate ceramics
Chen, Hui1,2; Guo, Shaobo1; Yao, Chunhua1; Dong, Xianlin1; Mao, Chaoliang1; Wang, Genshui1
刊名CERAMICS INTERNATIONAL
2017-03-01
卷号43期号:4页码:3610-3615
关键词Hot-pressing Pyroelectric properties Strontium barium niobate Lead-free ceramics
英文摘要Sr0.3Ba0.7Nb2O6 (SBN30) ferroelectric ceramics were fabricated by conventional sintering (CS) and by hot pressing sintering (HP) and their crystal structure, microstructure, dielectric, ferroelectric and pyroelectric properties were studied and compared. Preferred orientation of the HP ceramics was detected through X-ray diffraction. Dense microstructure virtually free of pores has been achieved in HP samples. Moreover, the HP samples manifested prominent anisotropy in electrical properties. Besides, the relative permittivity (er), saturated polarization (P-s,), pyroelectric coefficient (p) in the direction perpendicular to the pressing axis were much higher than those of the randomly oriented CS samples. The HP samples sintered under 200 MPa show excellent pyroelectric properties in the direction perpendicular to the pressing axis, with pyroelectric coefficient of 2.38x10(-8)C/cm(2)K and pyroelectric figure of merit of F-i=1.13 pm/V, F-v=1.89 m(2)/C and F-d=0.63 mu Pa-1/2 which roughly triple the values obtained in CS samples. These results indicate that hot-pressing is a viable option for accessing single-crystal-like anisotropy as well as enhanced electrical properties in polycrystalline ceramics, thus unveiling the distinctive potential of HP SBN30 ceramics for infrared detector applications.
WOS标题词Science & Technology ; Technology
类目[WOS]Materials Science, Ceramics
研究领域[WOS]Materials Science
关键词[WOS]PYROELECTRIC PROPERTIES ; SR1-XBAXNB2O6 ; SBN
收录类别SCI
语种英语
WOS记录号WOS:000393937900019
内容类型期刊论文
源URL[http://ir.sic.ac.cn/handle/331005/23556]  
专题上海硅酸盐研究所_无机功能材料与器件重点实验室_期刊论文
作者单位1.Chinese Acad Sci, Shanghai Inst Ceram, Key Lab Inorgan Funct Mat & Devices, 1295 Dingxi Rd, Shanghai 200050, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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GB/T 7714
Chen, Hui,Guo, Shaobo,Yao, Chunhua,et al. Induced anisotropic behavior and enhanced electrical properties on hot-pressed strontium barium niobate ceramics[J]. CERAMICS INTERNATIONAL,2017,43(4):3610-3615.
APA Chen, Hui,Guo, Shaobo,Yao, Chunhua,Dong, Xianlin,Mao, Chaoliang,&Wang, Genshui.(2017).Induced anisotropic behavior and enhanced electrical properties on hot-pressed strontium barium niobate ceramics.CERAMICS INTERNATIONAL,43(4),3610-3615.
MLA Chen, Hui,et al."Induced anisotropic behavior and enhanced electrical properties on hot-pressed strontium barium niobate ceramics".CERAMICS INTERNATIONAL 43.4(2017):3610-3615.
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