Catalytic conversion of substituted and un-substituted cyclohexanone into corresponding enones and phenols by nanocatalysts under acid or base-free reaction conditions

CORC > 西双版纳热带植物园 > 中国科学院西双版纳热带植物园 > 生物能源研究组

	Catalytic conversion of substituted and un-substituted cyclohexanone into corresponding enones and phenols by nanocatalysts under acid or base-free reaction conditions
	Shah, Mazloom ; Zhang, Fan ; Ahmad, Ashfaq
刊名	APPLIED CATALYSIS A-GENERAL
	2017
卷号	531 期号:x 页码:161-168
关键词	Metallic and bimetallic nanoparticles Heterogeneous nanocatalysts Catalytic conversion Cyclic ketones Enones and phenols
中文摘要	The catalytic conversion of substituted and unsubstituted cyclohexanones to the corresponding enones and aromatic alcohol catalyzed by Pd, Pd-1, Pd-cube, Cu, Ni, Ag@Pd and Ni-Sn nanocatalysts has been studied in the presence of O-2 as the oxidant without using any additives i.e. acid or base or ligand. The optimization of experimental parameters for dehydrogenation of cyclohexanones was established to achieve maximum yield of the product by using Pd nanocatalyst. The conversion of cyclohexanone, cyclohexenone, 3-methyl cyclohexanone and 3-methyl cyclohexenone catalyzed by Pd nanocatalyst at 80 degrees C, 10 atm O-2 pressure after 24 h, led to a 79%, 49%, 62% and 25% yields of desired products, respectively. Then, the conversion of substituted and unsubstituted cyclohexanones investigated in the presence of various nanocatalysts i.e., Pd-1, Pd-cube, Cu, Ni,Ag@Pd and Ni-Sn nanoparticles and was compared their percentage yields.
公开日期	2017-03-01
内容类型	期刊论文
源URL	[http://ir.xtbg.org.cn/handle/353005/10296]
专题	西双版纳热带植物园_生物能源研究组
推荐引用方式 GB/T 7714	Shah, Mazloom,Zhang, Fan,Ahmad, Ashfaq. Catalytic conversion of substituted and un-substituted cyclohexanone into corresponding enones and phenols by nanocatalysts under acid or base-free reaction conditions[J]. APPLIED CATALYSIS A-GENERAL,2017,531(x):161-168.
APA	Shah, Mazloom,Zhang, Fan,&Ahmad, Ashfaq.(2017).Catalytic conversion of substituted and un-substituted cyclohexanone into corresponding enones and phenols by nanocatalysts under acid or base-free reaction conditions.APPLIED CATALYSIS A-GENERAL,531(x),161-168.
MLA	Shah, Mazloom,et al."Catalytic conversion of substituted and un-substituted cyclohexanone into corresponding enones and phenols by nanocatalysts under acid or base-free reaction conditions".APPLIED CATALYSIS A-GENERAL 531.x(2017):161-168.