Study on the Crystal Structure of Cellulose in Bamboo with Synchrotron Radiation Wide Angle X-Ray Scattering | |
An, X; Yang, SM; Liu, R; Wei, PL; Yang, CM; Fei, BH | |
刊名 | SPECTROSCOPY AND SPECTRAL ANALYSIS
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2016 | |
卷号 | 36期号:11页码:3704-3708 |
关键词 | Bamboo Crystal structures of cellulose Synchrotron Radiation Wide Angle X-ray Scattering |
ISSN号 | 1000-0593 |
通讯作者 | Fei, BH (reprint author), Int Ctr Bamboo & Rattan, Key Lab Bamboo & Rattan Sci & Technol, Beijing 100102, Peoples R China. ; Yang, CM (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China. |
英文摘要 | The crystal structure of cellulose will directly affect the properties of bamboo fiber-reinforced composite, but the unit cell of native cellulose in bamboo has never been investigated. The most accepted model for the structure of native cellulose is Meyer-Misch model which provides a reference to understand the unit cell of native cellulose in bamboo. The native cellulose consists of two different crystal structures (I (alpha) and I (beta)) which exist in different plants with different proportions. Because of this situation, the crystal structure of bamboo cellulose should have a unique model. The moso bamboo (Phyllostachys edulis (Carr.) H. de Lehaie)was selected. The crystal structure of cellulose of bamboo was investigated with two dimensional synchrotron radiation wide angle X-ray scattering (SR-WAXS). The values of the interplanar spacings of each peak Were obtained from SR-WAXS patterns, and then crystal structure parameters were calculated according to monoclinic crystal system. The results show that the fibre axis of a bamboo cellulose unit cell with a monoclinic unit cell of a=8. 35 angstrom, b (fiber axis)=10. 38 angstrom, c=8. 02 angstrom, beta=84. 99 degrees. This model has a two antiparallel arrangement for the chains in unit cell, with four glucose residues. Thus, the model may be used to provide a theoretical basis for high value-added bamboo fiber-reinforced composite. |
收录类别 | SCI |
语种 | 中文 |
WOS记录号 | WOS:000388251100046 |
内容类型 | 期刊论文 |
源URL | [http://ir.sinap.ac.cn/handle/331007/26637] ![]() |
专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
推荐引用方式 GB/T 7714 | An, X,Yang, SM,Liu, R,et al. Study on the Crystal Structure of Cellulose in Bamboo with Synchrotron Radiation Wide Angle X-Ray Scattering[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2016,36(11):3704-3708. |
APA | An, X,Yang, SM,Liu, R,Wei, PL,Yang, CM,&Fei, BH.(2016).Study on the Crystal Structure of Cellulose in Bamboo with Synchrotron Radiation Wide Angle X-Ray Scattering.SPECTROSCOPY AND SPECTRAL ANALYSIS,36(11),3704-3708. |
MLA | An, X,et al."Study on the Crystal Structure of Cellulose in Bamboo with Synchrotron Radiation Wide Angle X-Ray Scattering".SPECTROSCOPY AND SPECTRAL ANALYSIS 36.11(2016):3704-3708. |
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