Study on the Crystal Structure of Cellulose in Bamboo with Synchrotron Radiation Wide Angle X-Ray Scattering
An, X; Yang, SM; Liu, R; Wei, PL; Yang, CM; Fei, BH
刊名SPECTROSCOPY AND SPECTRAL ANALYSIS
2016
卷号36期号:11页码:3704-3708
关键词Bamboo Crystal structures of cellulose Synchrotron Radiation Wide Angle X-ray Scattering
ISSN号1000-0593
通讯作者Fei, BH (reprint author), Int Ctr Bamboo & Rattan, Key Lab Bamboo & Rattan Sci & Technol, Beijing 100102, Peoples R China. ; Yang, CM (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China.
英文摘要The crystal structure of cellulose will directly affect the properties of bamboo fiber-reinforced composite, but the unit cell of native cellulose in bamboo has never been investigated. The most accepted model for the structure of native cellulose is Meyer-Misch model which provides a reference to understand the unit cell of native cellulose in bamboo. The native cellulose consists of two different crystal structures (I (alpha) and I (beta)) which exist in different plants with different proportions. Because of this situation, the crystal structure of bamboo cellulose should have a unique model. The moso bamboo (Phyllostachys edulis (Carr.) H. de Lehaie)was selected. The crystal structure of cellulose of bamboo was investigated with two dimensional synchrotron radiation wide angle X-ray scattering (SR-WAXS). The values of the interplanar spacings of each peak Were obtained from SR-WAXS patterns, and then crystal structure parameters were calculated according to monoclinic crystal system. The results show that the fibre axis of a bamboo cellulose unit cell with a monoclinic unit cell of a=8. 35 angstrom, b (fiber axis)=10. 38 angstrom, c=8. 02 angstrom, beta=84. 99 degrees. This model has a two antiparallel arrangement for the chains in unit cell, with four glucose residues. Thus, the model may be used to provide a theoretical basis for high value-added bamboo fiber-reinforced composite.
收录类别SCI
语种中文
WOS记录号WOS:000388251100046
内容类型期刊论文
源URL[http://ir.sinap.ac.cn/handle/331007/26637]  
专题上海应用物理研究所_中科院上海应用物理研究所2011-2017年
推荐引用方式
GB/T 7714
An, X,Yang, SM,Liu, R,et al. Study on the Crystal Structure of Cellulose in Bamboo with Synchrotron Radiation Wide Angle X-Ray Scattering[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2016,36(11):3704-3708.
APA An, X,Yang, SM,Liu, R,Wei, PL,Yang, CM,&Fei, BH.(2016).Study on the Crystal Structure of Cellulose in Bamboo with Synchrotron Radiation Wide Angle X-Ray Scattering.SPECTROSCOPY AND SPECTRAL ANALYSIS,36(11),3704-3708.
MLA An, X,et al."Study on the Crystal Structure of Cellulose in Bamboo with Synchrotron Radiation Wide Angle X-Ray Scattering".SPECTROSCOPY AND SPECTRAL ANALYSIS 36.11(2016):3704-3708.
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