Rh-Catalyzed Sequential Oxidative C-H and N-N Bond Activation: Conversion of Azines into Isoquinolines with Air at Room Temperature | |
Han, Wenjia2; Zhang GY(张国营)1![]() ![]() | |
刊名 | Organic Letters
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2014 | |
卷号 | 16期号:13页码:3532-3535 |
ISSN号 | 1523-7060 |
通讯作者 | 黄汉民 ; Li, Guangxing |
英文摘要 | A rhodium-catalyzed sequential oxidative C–H annulation reaction between ketazines and internal alkynes has been developed via C–H and N–N bond activation with air as an external oxidant, which led to an efficient approach toward isoquinolines with high atom efficiency at rt. Utilizing the distinctive reactivity of this catalysis, both N-atoms of the azines could be efficiently incorporated to the desired isoquinolines under very robust and mild reaction conditions. |
学科主题 | 物理化学与绿色催化 |
收录类别 | SCI |
资助信息 | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21222203;21133011;21372231) |
语种 | 英语 |
WOS记录号 | WOS:000340808000029 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/21303] ![]() |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Wuhan 430074, Peoples R China |
推荐引用方式 GB/T 7714 | Han, Wenjia,Zhang GY,Li, Guangxing,et al. Rh-Catalyzed Sequential Oxidative C-H and N-N Bond Activation: Conversion of Azines into Isoquinolines with Air at Room Temperature[J]. Organic Letters,2014,16(13):3532-3535. |
APA | Han, Wenjia,Zhang GY,Li, Guangxing,&Huang HM.(2014).Rh-Catalyzed Sequential Oxidative C-H and N-N Bond Activation: Conversion of Azines into Isoquinolines with Air at Room Temperature.Organic Letters,16(13),3532-3535. |
MLA | Han, Wenjia,et al."Rh-Catalyzed Sequential Oxidative C-H and N-N Bond Activation: Conversion of Azines into Isoquinolines with Air at Room Temperature".Organic Letters 16.13(2014):3532-3535. |
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