Sr2Fe1+xMo1-xO6-delta as anode material of cathode-supported solid oxide fuel cells
Miao, Guoshuan; Yuan, Chun; Chen, Ting; Zhou, Yucun; Than, Weiting; Wang, Shaorong
刊名INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
2016-01-12
卷号41期号:2页码:1104-1111
关键词Molybdenum doped strontium ferrite Anode Cathode-supported Solid oxide fuel cell
英文摘要In this study, perovskite-type oxides of Sr2Fe1+xMo1-xO6-delta, (x = 0, 0.2, 0.35, 0.5) were synthesized and the phase stabilities both in oxidizing and reducing atmosphere were investigated. When calcined in the air atmosphere, pure perovskite phase can be obtained for the composition of Sr2Fe1.5Mo0.5O6-delta while a large portion of SrMoO4 second phase was detected in other compositions. Further reducing the above powders showed a pure phase for Sr2Fe1+xMo1-xO6-delta (x = 0, 0.2, 0.35) while minor amount of Fe was precipitated from the Sr2Fe1.5Mo0.5O6-delta. Due to the highest electrical conductivity and lowest polarization resistance of Sr2FeMoO6-delta, such composition has been applied as the cell anode for a cathode supported solid oxide fuel cell (CS-SOFC). Maximum power densities of 463 and 331 mW cm(-2) have obtained for the fuel cell when measured at 800 degrees C using hydrogen and propane as fuel, respectively. The durability test in propane indicated that Sr2FeMoO6-delta could be a potential anode material with good tolerance ability toward coking formation. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Physical ; Electrochemistry ; Energy & Fuels
研究领域[WOS]Chemistry ; Electrochemistry ; Energy & Fuels
关键词[WOS]SR2FE1.5MO0.5O6-DELTA PEROVSKITE ; CARBON FORMATION ; OXIDATION ; METHANE ; PERFORMANCE ; PROGRESS
收录类别SCI
语种英语
WOS记录号WOS:000369202900041
内容类型期刊论文
源URL[http://ir.sic.ac.cn/handle/331005/23249]  
专题上海硅酸盐研究所_能量转换材料重点实验室_期刊论文
作者单位Chinese Acad Sci SICCAS, Shanghai Inst Ceram, CAS Key Lab Mat Energy Convers, 1295 Ding Xi Rd, Shanghai 200050, Peoples R China
推荐引用方式
GB/T 7714
Miao, Guoshuan,Yuan, Chun,Chen, Ting,et al. Sr2Fe1+xMo1-xO6-delta as anode material of cathode-supported solid oxide fuel cells[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2016,41(2):1104-1111.
APA Miao, Guoshuan,Yuan, Chun,Chen, Ting,Zhou, Yucun,Than, Weiting,&Wang, Shaorong.(2016).Sr2Fe1+xMo1-xO6-delta as anode material of cathode-supported solid oxide fuel cells.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,41(2),1104-1111.
MLA Miao, Guoshuan,et al."Sr2Fe1+xMo1-xO6-delta as anode material of cathode-supported solid oxide fuel cells".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 41.2(2016):1104-1111.
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