All Symmetrical Metal Supported Solid Oxide Fuel Cells | |
Zhou Yu-Cun; Ye Xiao-Feng; Wang Shao-Rong | |
刊名 | JOURNAL OF INORGANIC MATERIALS |
2016-07-20 | |
卷号 | 31期号:7页码:769-772 |
关键词 | metal supported solid oxide fuel cell ceria |
英文摘要 | Metal-supported solid oxide fuel cells (MS-SOFCs) have many advantages like low materials cost, excellent structural stability and high tolerance toward rapid thermal cycling over the traditional all ceramic SOFCs. To facilitate the commercialization of SOFCs, an all symmetrical MS-SOFC with the structure of Ce0.8Sm0.2O2-delta (SDC)-430L anode/Zr0.88Sc0.22Ce0.01O2.12(SSZ) electrolyte/SDC-430L cathode was developed by a tape casting-sintering-infiltration method. When measured in humidified hydrogen fuel and air oxidant, the maximum power densities (MPD) of the fuel cell are 220, 250 and 280 mW/cm(2) at 600, 650 and 700 degrees C, respectively. Electrochemical impedance spectra measurement shows that the cell performances are primarily dominated by polarization resistances derived from the SDC-430L electrodes. The pure ohmic resistances are 0.16, 0.21 and 0.29 Omega.cm(2) and the polarization resistances are 0.67, 0.90 and 1.22 Omega.cm(2) at 700, 650 and 600 degrees C, respectively. Compared with that of the anode, polarization resistance of cathode is much higher. When measured at 650 degrees C, polarization resistances of the symmetrical SDC-430L cell are 0.23 and 1.92 Omega.cm(2) in 3% H2O-97% H-2 and air, respectively. Further optimizing the cell structure (e.g., applying a finer 430L backbone) and the catalyst materials (e.g., Ag, Pt containing composite materials) may enhance the electrochemical performances of such MS-SOFC. |
WOS标题词 | Science & Technology ; Technology |
类目[WOS] | Materials Science, Ceramics |
研究领域[WOS] | Materials Science |
关键词[WOS] | DIFFUSION BARRIER LAYERS ; SOFC ; STABILITY ; ANODES |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000383394800016 |
内容类型 | 期刊论文 |
源URL | [http://ir.sic.ac.cn/handle/331005/22842] |
专题 | 上海硅酸盐研究所_能量转换材料重点实验室_期刊论文 |
作者单位 | Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China |
推荐引用方式 GB/T 7714 | Zhou Yu-Cun,Ye Xiao-Feng,Wang Shao-Rong. All Symmetrical Metal Supported Solid Oxide Fuel Cells[J]. JOURNAL OF INORGANIC MATERIALS,2016,31(7):769-772. |
APA | Zhou Yu-Cun,Ye Xiao-Feng,&Wang Shao-Rong.(2016).All Symmetrical Metal Supported Solid Oxide Fuel Cells.JOURNAL OF INORGANIC MATERIALS,31(7),769-772. |
MLA | Zhou Yu-Cun,et al."All Symmetrical Metal Supported Solid Oxide Fuel Cells".JOURNAL OF INORGANIC MATERIALS 31.7(2016):769-772. |
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