Preferential Facet Growth of Methylammonium Lead Halide Single Crystals Promoted by Halide Coordination
Zhang, Yi1,2; Huang, Fuqiang1,2; Mi, Qixi2
刊名CHEMISTRY LETTERS
2016-08-05
卷号45期号:8页码:1030-1032
关键词Perovskite solar cell Crystal facet growth Dodecahedra and cuboid
英文摘要

Perovskite solar cells utilize solution-processed CH3NH3PbI3 thin films as the active layer material, whose morphology and exposed facets directly contribute to the device efficiency and stability. We investigated various conditions for growing CH3NH3PbX3 (X = Br, I) crystals from solutions, and found that bromide, nonaqueous solvents, and higher X-/PbX2 ratios favor the growth of cuboids over dodecahedra. We propose that these factors promote the coordination of X- to Pb2+ on the growing surfaces, thus making the {111}(c) faces outgrow the {100}(c) faces.

WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]PEROVSKITE SOLAR-CELLS ; I CRYSTALS ; BR ; DIFFUSION
收录类别SCI
语种英语
WOS记录号WOS:000381541700062
内容类型期刊论文
源URL[http://ir.sic.ac.cn/handle/331005/22865]  
专题上海硅酸盐研究所_高性能陶瓷和超微结构国家重点实验室_期刊论文
作者单位1.Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China
2.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Yi,Huang, Fuqiang,Mi, Qixi. Preferential Facet Growth of Methylammonium Lead Halide Single Crystals Promoted by Halide Coordination[J]. CHEMISTRY LETTERS,2016,45(8):1030-1032.
APA Zhang, Yi,Huang, Fuqiang,&Mi, Qixi.(2016).Preferential Facet Growth of Methylammonium Lead Halide Single Crystals Promoted by Halide Coordination.CHEMISTRY LETTERS,45(8),1030-1032.
MLA Zhang, Yi,et al."Preferential Facet Growth of Methylammonium Lead Halide Single Crystals Promoted by Halide Coordination".CHEMISTRY LETTERS 45.8(2016):1030-1032.
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