Highly Stable Eu(III) and Tb(III) Complexes Based on Triarylborane-Functionalized Cyclen Derivatives as Visual Temperature Probes and White-Light Emitters

	Highly Stable Eu(III) and Tb(III) Complexes Based on Triarylborane-Functionalized Cyclen Derivatives as Visual Temperature Probes and White-Light Emitters
	Wang, Suning 1,2; Wu, Tian-Ze 1; Park, Hee-Jun 2; Peng, Tai 1; Cao, Li-Xia 3; Mellerup, Soren K.2; Yang, Guo-Qiang 3; Wang, Nan 1; Peng, Jin-Bao 2
刊名	ADVANCED OPTICAL MATERIALS
	2016-11-01
卷号	4 期号:11 页码:1882-1892
英文摘要	New and highly stable Eu(III) and Tb(III) complexes based on two triarylborane functionalized cyclen derivative ligands L1 and L2, have been achieved. The Eu(III) and Tb(III) lanthanide compounds have been found to display highly distinct and contrasting temperature-dependent dual emission and decay lifetimes, rendering them as potential sensitive temperature probes. The emission colors of the new lanthanide complexes can be tuned by controlling the ratio of the Eu(III) and Tb(III) complexes in a binary composite and the temperature. Bright white light emission based on the new binary Eu(III) and Tb(III) complexes has been achieved. Furthermore, the triarylborane functionality of the new complexes enables their use as effective probes for anions such as fluoride ions, allowing the further tuning of the lanthanide emission.
收录类别	SCI
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/36541]
专题	化学研究所_光化学实验室
作者单位	1.Beijing Inst Technol China, Sch Chem, Beijing Key Lab Photoelect Electrophoton Convers, Beijing 102488, Peoples R China 2.Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada 3.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Wang, Suning,Wu, Tian-Ze,Park, Hee-Jun,et al. Highly Stable Eu(III) and Tb(III) Complexes Based on Triarylborane-Functionalized Cyclen Derivatives as Visual Temperature Probes and White-Light Emitters[J]. ADVANCED OPTICAL MATERIALS,2016,4(11):1882-1892.
APA	Wang, Suning.,Wu, Tian-Ze.,Park, Hee-Jun.,Peng, Tai.,Cao, Li-Xia.,...&Peng, Jin-Bao.(2016).Highly Stable Eu(III) and Tb(III) Complexes Based on Triarylborane-Functionalized Cyclen Derivatives as Visual Temperature Probes and White-Light Emitters.ADVANCED OPTICAL MATERIALS,4(11),1882-1892.
MLA	Wang, Suning,et al."Highly Stable Eu(III) and Tb(III) Complexes Based on Triarylborane-Functionalized Cyclen Derivatives as Visual Temperature Probes and White-Light Emitters".ADVANCED OPTICAL MATERIALS 4.11(2016):1882-1892.