Zirconyldichloride Modified Polycarbosilazane as Precursors for SiZrCNO Ceramics

	Zirconyldichloride Modified Polycarbosilazane as Precursors for SiZrCNO Ceramics
	Han Jiajie; Su Dong; Yu Yang; Zhao Xueting; Wang Xiaojing; Zhao Zhipeng; Yan Xiao; Jin Zhengguo
刊名	Key Engineering Materials
	2016
英文摘要	Zirconyldichloride modified polycarbosilazane (PZrSZO) has been synthesized from two-component dichlorosilanes (methyldichlorosilane and methylvinyldichlorosilane), zirconyldichloride, and ethylenediamine using triethylamine as acid-absorbing agent and tetrahydrofuran as solvent. 1H nuclear magnetic resonance analysis of the as-synthesized PZrSZO suggest a structure of ethylene-bridged polycarbosilazane having –Si–N–C–C–N– as backbone chain with –CH=CH2, –H and –CH3 attached to Si as side groups, which is similar to that of non-modified PSZO precursor. Fourier transform infrared spectroscopy shows Zr–N stretching vibration peak appears at 532 cm-1 suggesting the incorporation of Zr into PSZO through aminolysis reaction between zirconyldichloride and ethylendiamine. SiZrCNO ceramic with the ceramic yield of 63 wt% is obtained through subsequent pyrolysis treatment at 1000 °C for 1 h under argon flow. EDS analysis shows its composition of SiZr0.01C1.03N0.25O0.84 with the Zr percentage of 1.45 wt%. X-ray diffraction analysis shows SiZrCNO ceramics are of mixed amorphous silicon carbonitride oxygen phase embraced with SiO2 nanocrystalline.
收录类别	SCI
原文出处	http://www.scientific.net/KEM.697.153
语种	英语
内容类型	期刊论文
源URL	[http://ir.siat.ac.cn:8080/handle/172644/9744]
专题	深圳先进技术研究院_南沙所
作者单位	Key Engineering Materials
推荐引用方式 GB/T 7714	Han Jiajie,Su Dong,Yu Yang,et al. Zirconyldichloride Modified Polycarbosilazane as Precursors for SiZrCNO Ceramics[J]. Key Engineering Materials,2016.
APA	Han Jiajie.,Su Dong.,Yu Yang.,Zhao Xueting.,Wang Xiaojing.,...&Jin Zhengguo.(2016).Zirconyldichloride Modified Polycarbosilazane as Precursors for SiZrCNO Ceramics.Key Engineering Materials.
MLA	Han Jiajie,et al."Zirconyldichloride Modified Polycarbosilazane as Precursors for SiZrCNO Ceramics".Key Engineering Materials (2016).