Photocatalytic Asymmetric Epoxidation of Terminal Olefins Using Water as an Oxygen Source in the Presence of a Mononuclear Non-Heme Chiral Manganese Complex | |
Shen DY(沈都益)1![]() ![]() | |
刊名 | Journal of the American Chemical Society
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2016 | |
卷号 | 138期号:49页码:15857-15860 |
ISSN号 | 0002-7863 |
通讯作者 | Wonwoo Nam ; Shunichi Fukuzumi ; 孙伟 |
英文摘要 | Photocatalytic enantioselective epoxidation of terminal olefins using a mononuclear non-heme chiral manganese catalyst, [(R,R-BQCN)MnII]2+, and water as an oxygen source yields epoxides with relatively high enantioselectivities (e.g., up to 60% enantiomeric excess). A synthetic mononuclear non-heme chiral Mn(IV)–oxo complex, [(R,R-BQCN)MnIV(O)]2+, affords similar enantioselectivities in the epoxidation of terminal olefins under stoichiometric reaction conditions. Mechanistic details of each individual step of the photoinduced catalysis, including formation of the Mn(IV)–oxo intermediate, are discussed on the basis of combined results of laser flash photolysis and other spectroscopic methods. |
学科主题 | 物理化学与绿色催化 |
收录类别 | SCI |
资助信息 | the NRF of Korea through the CRI (NRF-2012R1A3A2048842 to W.N.);GRL (NRF-2010-00353 to W.N.) Programs;JSPS KAKENHI (16H02268 to S.F.);the National Natural Science Foundation of China (21473226 to S.W.);the National Research Foundation of Korea (Grant NRF-2015H1D3A1066507) |
语种 | 英语 |
WOS记录号 | WOS:000389962800016 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/21209] ![]() |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
作者单位 | 1.Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 03760, South Korea 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 3.Meijo Univ, Japan Sci & Technol Agcy JST, SENTAN, Fac Sci & Engn, Nagoya, Aichi 4688502, Japan |
推荐引用方式 GB/T 7714 | Shen DY,Claudio Saracini,Yong-Min Lee,et al. Photocatalytic Asymmetric Epoxidation of Terminal Olefins Using Water as an Oxygen Source in the Presence of a Mononuclear Non-Heme Chiral Manganese Complex[J]. Journal of the American Chemical Society,2016,138(49):15857-15860. |
APA | Shen DY,Claudio Saracini,Yong-Min Lee,Sun W,Shunichi Fukuzumi,&Wonwoo Nam.(2016).Photocatalytic Asymmetric Epoxidation of Terminal Olefins Using Water as an Oxygen Source in the Presence of a Mononuclear Non-Heme Chiral Manganese Complex.Journal of the American Chemical Society,138(49),15857-15860. |
MLA | Shen DY,et al."Photocatalytic Asymmetric Epoxidation of Terminal Olefins Using Water as an Oxygen Source in the Presence of a Mononuclear Non-Heme Chiral Manganese Complex".Journal of the American Chemical Society 138.49(2016):15857-15860. |
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