Semiconductive K2MSbS3(SH) (M = Zn, Cd) Featuring One-Dimensional (1)(infinity)[M2Sb2S6(SH2)](4-) Chains | |
Zhang, Xian1,2; Yi, Na3; Hoffmann, Roald4; Zheng, Chong5; Lin, Jianhua1,2; Huang, Fuqiang1,2,3 | |
刊名 | INORGANIC CHEMISTRY
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2016-10-03 | |
卷号 | 55期号:19页码:9742-9747 |
英文摘要 | We synthesized two one-dimensional compounds K2MSbS3(SH) (M = Zn, Cd) at 473 K, using thiourea as reactive flux. The compounds crystallize in the triclinic space group P (1) over bar. Their structures feature one-dimensional (1)(infinity)[M2Sb2S6(SH2)](4-) double chains along the crystallographic a axis. The (1)(infinity)[M2Sb2S6(SH2)](4-) double chains are composed of [M2Sb2S8(SH)(2)](8-) eight-membered rings. Similar band gaps of the two compounds, E-g = 2.75 eV for K2ZnSbS3(SH) and E-g = 171 eV for K2CdSbS3(SH), were obtained from optical absorption measurements, which are consistent with theoretical calculations. The analysis of density of states indicates that the valence band maximum and conduction band minimum consist mainly of S-3p orbitals and Sb-5p orbitals, respectively. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Inorganic & Nuclear |
研究领域[WOS] | Chemistry |
关键词[WOS] | CRYSTAL-STRUCTURE ; ELECTRONIC-STRUCTURE ; PHYSICAL-PROPERTIES ; RESPONSE PROPERTIES ; BISMUTH OXYSULFIDE ; SE ; CHALCOGENIDES ; REDUCTION ; ORBITALS ; BI2O2S |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000384782600031 |
内容类型 | 期刊论文 |
源URL | [http://ir.sic.ac.cn/handle/331005/22046] ![]() |
专题 | 上海硅酸盐研究所_高性能陶瓷和超微结构国家重点实验室_期刊论文 |
作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China 4.Cornell Univ, Dept Chem & Chem Biol, Ithaca, NY 14853 USA 5.Northern Illinois Univ, Dept Chem & Biochem, De Kalb, IL 60115 USA |
推荐引用方式 GB/T 7714 | Zhang, Xian,Yi, Na,Hoffmann, Roald,et al. Semiconductive K2MSbS3(SH) (M = Zn, Cd) Featuring One-Dimensional (1)(infinity)[M2Sb2S6(SH2)](4-) Chains[J]. INORGANIC CHEMISTRY,2016,55(19):9742-9747. |
APA | Zhang, Xian,Yi, Na,Hoffmann, Roald,Zheng, Chong,Lin, Jianhua,&Huang, Fuqiang.(2016).Semiconductive K2MSbS3(SH) (M = Zn, Cd) Featuring One-Dimensional (1)(infinity)[M2Sb2S6(SH2)](4-) Chains.INORGANIC CHEMISTRY,55(19),9742-9747. |
MLA | Zhang, Xian,et al."Semiconductive K2MSbS3(SH) (M = Zn, Cd) Featuring One-Dimensional (1)(infinity)[M2Sb2S6(SH2)](4-) Chains".INORGANIC CHEMISTRY 55.19(2016):9742-9747. |
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